Indolo[3,2,1-jk]carbazole

Base Information

• Chemical Name: Indolo[3,2,1-jk]carbazole
• CAS No.: 205-95-8
• Molecular Formula: C₁₈H₁₁N
• Molecular Weight: 241.292
• Mol file: 205-95-8.mol

Synonyms:indolo<3,2,1-jk>carbazole

Chemical Property of Indolo[3,2,1-jk]carbazole

Chemical Property:

• Melting Point: 134.0 to 138.0 °C
• Boiling Point: 392.1±15.0 °C(Predicted)
• Density: 1.26±0.1 g/cm3(Predicted)
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

Indolo[3,2,1-jk]carbazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Indolo[3,2,1-jk]carbazole

There total 25 articles about Indolo[3,2,1-jk]carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

9-(2-bromophenyl)-9H-carbazole (902518-11-0) → indolo<3,2,1-jk>carbazole (205-95-8)

Guidance literature:

With palladium diacetate; tricyclohexylphosphine; In N,N-dimethyl acetamide; Reflux;

Reference yield: 73.0%

N-phenylcarbazole (1150-62-5) → indolo<3,2,1-jk>carbazole (205-95-8)

Guidance literature:

With palladium(II) trimethylacetate; oxygen; copper(II) oxide; silver(l) oxide; Trimethylacetic acid; at 130 ℃; for 24h; under 760.051 Torr; Reagent/catalyst; Temperature;

DOI:10.1002/adsc.201401136

Reference yield: 72.0%

2-(9H-carbazol-9-yl)aniline (101716-43-2) → indolo<3,2,1-jk>carbazole (205-95-8)

Guidance literature:

With sulfuric acid; sodium nitrite; In water; acetic acid; at 10 - 130 ℃; for 0.75h; Cooling with ice;

upstream raw materials:

2-(9H-carbazol-9-yl)aniline

9-phenyl-9H-carbazol-1-amine

indolo[3,2,1-jk]carbazole-5-carboxylic acid

9H-carbazole-3-carboxylic acid

Downstream raw materials:

5-bromoindolo[3,2,1-jk]carbazole

2-bromoindolo[3,2,1-jk]carbazole

C₃₀H₁₈BrN

C₅₄H₃₆N₂

Refernces

• 1、 -. "Composition For Capping Layer of Organic Light Emitting Diode and Organic Light Emitting Diode Having The Same". . . Retrieved 2021/02/16.
• 2、 Liao, Xiang-Ji,Lu, Jun-Jian,Luo, Xu-Feng,Yan, Zhi-Ping,Yuan, Li,Zhang, Yi-Pin,Zheng, You-Xuan,Zhu, Jin-Jun. "Efficient organic light-emitting diodes based on iridium(iii) complexes containing indolo[3,2,1-jk]carbazole derivatives with narrow emission bandwidths and low efficiency roll-offs". . p. 8226 - 8232. Retrieved 2021/07/13.