4-NITRODIPHENYLMETHANE

Base Information

• Chemical Name: 4-NITRODIPHENYLMETHANE
• CAS No.: 1817-77-2
• Molecular Formula: C13H11 N O2
• Molecular Weight: 213.236
• Hs Code.: 2904209090
• Mol file: 1817-77-2.mol

Synonyms:Methane,(p-nitrophenyl)phenyl- (6CI,7CI,8CI); (p-Nitrophenyl)phenylmethane;4-Benzylnitrobenzene; 4-Nitrodiphenylmethane; NSC 631623; NSC 97261;p-Nitrodiphenylmethane

Chemical Property of 4-NITRODIPHENYLMETHANE

Chemical Property:

• Melting Point: 31 °C
• Refractive Index: n20/D 1.6040(lit.)
• Boiling Point: 351.9°Cat760mmHg
• Flash Point: 164.3°C
• PSA: 45.82000
• Density: 1.18g/cm³
• LogP: 3.70880
• Storage Temp.: Inert atmosphere,Room Temperature

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-Nitrodiphenylmethane ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 43
• Safety Statements: 36/37

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-NITRODIPHENYLMETHANE

There total 64 articles about 4-NITRODIPHENYLMETHANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

4-nitrobenzyl chloride (100-14-1) + phenylboronic acid (98-80-6) → 4-benzyl-1-nitrobenzene (1817-77-2)

Guidance literature:

With potassium phosphate tribasic trihydrate; In toluene; at 80 ℃; for 0.5h; Solvent; Temperature; Inert atmosphere;

DOI:10.1039/c4ra06551d

Reference yield: 99.0%

4-nitrobenzophenone (1144-74-7) → 4-benzyl-1-nitrobenzene (1817-77-2)

Guidance literature:

With gallium(III) triflate; dimethylmonochlorosilane; In dichloromethane; at 20 ℃; for 0.5h;

DOI:10.1007/s10562-011-0551-0

Reference yield: 95.0%

4-nitrophenyl(phenyl)methanol (33091-15-5) → 4-benzyl-1-nitrobenzene (1817-77-2)

Guidance literature:

With indium(III) chloride; diphenylsilyl chloride; In dichloromethane; at 20 ℃; for 3h;

DOI:10.1021/jo0158534

upstream raw materials:

4-nitrobenzyl chloride

benzene

4-nitrobenzyl chloride

4-nitrobenzophenone

Downstream raw materials:

1,4-bis-(4-nitro-benzyl)-benzene

C₁₉H₁₅N₃O₆S

4-benzoylamino-4'-(4-benzoylamino-benzyl)-benzophenone

1,4-bis-(4-nitro-benzoyl)-benzene

Refernces

• 1、 Cain,Holler. "Extended scope of in situ iodotrimethylsilane mediated selective reduction of benzylic alcohols". . p. 1168 - 1169. Retrieved 2001.
• 2、 Balaraman, Kaluvu,Wolf, Christian. "Palladium and Nickel Catalyzed Suzuki Cross-Coupling with Alkyl Fluorides". supporting information. p. 8994 - 8999. Retrieved 2021/11/20.
• 3、 Rafiee, Ezzat,Joshaghani, Mohammad,Abadi, Parvaneh Ghaderi-Shekhi. "Unmodified Fe3O4 nanostructure promoted with external magnetic field: safe, magnetically recoverable, and efficient nanocatalyst for N- and C-alkylation reactions in green conditions". . p. 2503 - 2522. Retrieved 2018/01/04.