4-nitrophenylthiolate

Base Information

• Chemical Name: 4-nitrophenylthiolate
• CAS No.: 45797-13-5
• Molecular Formula: C₆H₄NO₂S
• Molecular Weight: 154.169
• Mol file: 45797-13-5.mol

Synonyms:4-nitrophenylthiolate

Chemical Property of 4-nitrophenylthiolate

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-nitrophenylthiolate

There total 53 articles about 4-nitrophenylthiolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

para-nitrobenzenethiol (1849-36-1) → di(p-nitrophenyl) disulfide (100-32-3) + p-nitrophenylsulfanyl radical (72182-62-8) + 4-nitrophenylthiolate (45797-13-5)

Guidance literature:

In tetrahydrofuran; Further Variations:; Solvents; also in the presence of triplet-quenching reagents; Quantum yield; Kinetics;

DOI:10.1021/jo982133x

Reference yield:

0,0-Diphenyl-S-(4-nitrophenyl)-thiophosphat (55011-56-8) → diphenyl hydrogen phosphate (838-85-7) + 4-nitrophenylthiolate (45797-13-5)

Guidance literature:

With hydroxide; In water; acetonitrile; at 25 ℃; Rate constant; various solvents; solvent effects investigated;

DOI:10.1002/(sici)1099-1395(199704)10:4<221::aid-poc868>3.0.co;2-b

Reference yield:

1-acetylsulfanyl-4-nitro-benzene (15119-62-7) → acetamide (60-35-5) + 4-nitrophenylthiolate (45797-13-5)

Guidance literature:

With potassium chloride; ammonium chloride; ammonia; In 1,4-dioxane; water; at 18 ℃; pH=9.40; Further Variations:; pH-values; Kinetics;

DOI:10.1002/kin.10014

upstream raw materials:

Nitroethane

di(p-nitrophenyl) disulfide

hydrogen cyanide

S-(4-nitrophenyl) thiocarbamate

Downstream raw materials:

1,2-bis(5-nitro-2-furyl)ethane

2-nitro-5-(4-nitro-phenylsulfanylmethyl)-furan

di(p-nitrophenyl) disulfide

2-methyl-5-nitrofuran

Refernces

• 1、 Castro, Enrique A.,Gazitua, Marcela,Santos, Jose G.. "Reactions of O-aryl S-aryl dithiocarbonates with secondary alicyclic amines in aqueous ethanol. Kinetics and mechanism". supporting information; scheme or table. p. 466 - 473. Retrieved 2012/01/19.
• 2、 Castro, Enrique A.,Gazitua, Marcela,Santos, Jose G.. "Reactions of O-aryl S-aryl dithiocarbonates with pyridines in aqueous ethanol: Kinetics and mechanism". scheme or table. p. 1003 - 1008. Retrieved 2010/07/04.