Cyclohexylmethyl acetate

Base Information

• Chemical Name: Cyclohexylmethyl acetate
• CAS No.: 937-55-3
• Molecular Formula: C9H16O2
• Molecular Weight: 156.225
• Hs Code.: 2916200090
• Mol file: 937-55-3.mol

Synonyms:cyclohexylmethyl acetate;

Chemical Property of Cyclohexylmethyl acetate

Chemical Property:

• Vapor Pressure: 0.385mmHg at 25°C
• Refractive Index: 1.4430-1.4470
• Boiling Point: 197.1°C at 760 mmHg
• Flash Point: 66.8°C
• PSA: 26.30000
• Density: 0.952g/cm³
• LogP: 2.12980

Purity/Quality:

98%,99%, ^*data from raw suppliers

Cyclohexylmethyl Acetate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cyclohexylmethyl acetate

There total 20 articles about Cyclohexylmethyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

vinyl acetate (108-05-4,9003-20-7) + cyclohexylmethyl alcohol (100-49-2) → cyclohexylmethyl acetate (937-55-3)

Guidance literature:

With Cp*2Sm(THF)2; In toluene; for 0.000833333h; Ambient temperature;

DOI:10.1021/jo952168m

Reference yield: 94.0%

acetic anhydride (108-24-7) + cyclohexylmethyl alcohol (100-49-2) → cyclohexylmethyl acetate (937-55-3)

Guidance literature:

With potassium tropolonato; In acetonitrile; at 70 ℃; for 4h;

DOI:10.1021/acscatal.0c03702

Reference yield: 86.0%

acetic anhydride (108-24-7) + 2-(methoxyethoxy)methyl cyclohexylmethyl ether (114968-46-6) → cyclohexylmethyl acetate (937-55-3)

Guidance literature:

With iron(III) chloride; In 1,2-dichloro-ethane; at 25 ℃; for 18h;

upstream raw materials:

acetic anhydride

cyclohexylmethyl alcohol

acetyl chloride

mercury(II) diacetate

Downstream raw materials:

methylenecyclohexane

cyclohexylmethyl alcohol

O-2-phenylethyl ethanethioate

ethanol

Refernces

• 1、 Mai, Binh Khanh,Koenigs, Rene M.,Nguyen, Thanh Vinh,Lyons, Demelza J.M.,Empel, Claire,Pace, Domenic P.,Dinh, An H.. "Tropolonate salts as acyl-transfer catalysts under thermal and photochemical conditions: Reaction scope and mechanistic insights". . p. 12596 - 12606. Retrieved 2020/11/18.
• 2、 Toyao, Takashi,Nurnobi Rashed, Md.,Morita, Yoshitsugu,Kamachi, Takashi,Hakim Siddiki,Ali, Md. A.,Touchy,Kon, Kenichi,Maeno, Zen,Yoshizawa, Kazunari,Shimizu, Ken-ichi. "Esterification of Tertiary Amides by Alcohols Through C?N Bond Cleavage over CeO2". . p. 449 - 456. Retrieved 2018/09/11.