(Isooctadecanoato-O)bis(methacrylato-O)(propan-2-olato)titanium

Base Information

• Chemical Name: (Isooctadecanoato-O)bis(methacrylato-O)(propan-2-olato)titanium
• CAS No.: 61548-33-2
• Deprecated CAS: 58766-23-7,80057-44-9
• Molecular Formula: C₄H₆O
• Molecular Weight: 70.091
• European Community (EC) Number: 262-836-4
• Mol file: 61548-33-2.mol

Synonyms:isopropyl dimethacryloyl isostearoyl titanate;KR-7

Chemical Property of (Isooctadecanoato-O)bis(methacrylato-O)(propan-2-olato)titanium

Chemical Property:

• Vapor Pressure: 1.52E-07mmHg at 25°C
• Boiling Point: 400.8 °C at 760 mmHg
• Flash Point: 225.6 °C
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 17
• Exact Mass: 564.3505448
• Heavy Atom Count: 37
• Complexity: 549

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)CCCCCCCCCCCCCCC(=O)O.CC(C)O.CC(=C)C(=O)O.CC(=C)C(=O)O.[Ti]

Technology Process of (Isooctadecanoato-O)bis(methacrylato-O)(propan-2-olato)titanium

There total 26 articles about (Isooctadecanoato-O)bis(methacrylato-O)(propan-2-olato)titanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.5%

buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) → epoxybutene (930-22-3,62249-81-4) + 1,2:3,4-Diepoxybutane (564-00-1,1464-53-5,30031-64-2,30419-67-1,34897-03-5,298-18-0)

Guidance literature:

With sodium oxalate; oxalic acid; manganese(II) acetate; N,N',N''-trimethyl-1,4,7-triazacyclononane; In water;

buta-1,3-diene; With dihydrogen peroxide; In water; at -40 - 25 ℃; for 8.5h; under 2400.24 - 3900.39 Torr; Cooling with acetone-dry ice;

Reference yield: 92.0%

buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) → epoxybutene (930-22-3,62249-81-4)

Guidance literature:

With [N,N'-bis(salicylidene)-1,2-ethanediaminato]Mn(III) chloride; iodosylbenzene; In dichloromethane;

DOI:10.1039/c39920001072

Reference yield:

ethylbenzene (100-41-4,27536-89-6) + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) → epoxybutene (930-22-3,62249-81-4) + 1-Phenylethanol (98-85-1,13323-81-4)

Guidance literature:

ethylbenzene; With air; at 160 ℃; under 3000.3 Torr;

buta-1,3-diene; With 1.6 weight percent Ti-HMS catalyst; at 105 ℃; for 24h; under 26252.6 Torr; Temperature; Pressure; Reagent/catalyst;

upstream raw materials:

(2-bromoethyl)oxirane

sodium diethylmalonate

ethanol

1-chloro-2-hydroxy-3-butene

Refernces

• 1、 Monnier, John R.,Medlin,Barteau. "Use of oxygen-18 to determine kinetics of butadiene epoxidation over Cs-promoted, Ag catalysts". . p. 362 - 368. Retrieved 2001.
• 2、 Solís-Mu?ana, Pablo,Salam, Joanne,Ren, Chloe Z.-J.,Carr, Bronte,Whitten, Andrew E.,Warr, Gregory G.,Chen, Jack L.-Y.. "An Amphiphilic (salen)Co Complex – Utilizing Hydrophobic Interactions to Enhance the Efficiency of a Cooperative Catalyst". supporting information. p. 3207 - 3213. Retrieved 2021/06/01.
• 3、 Wu, Mei,Zhao, Huahua,Yang, Jian,Zhao, Jun,Song, Huanling,Chou, Lingjun. "Precursor effect on the property and catalytic behavior of Fe-TS-1 in butadiene epoxidation". . p. 2103 - 2109. Retrieved 2017/10/06.