3-oxocyclohexancarboxyaldehyde ethylenacetal

Base Information

• Chemical Name: 3-oxocyclohexancarboxyaldehyde ethylenacetal
• CAS No.: 123762-05-0
• Molecular Formula: C₉H₁₄O₃
• Molecular Weight: 170.208
• Mol file: 123762-05-0.mol

Synonyms:3-oxocyclohexancarboxyaldehyde ethylenacetal

Chemical Property of 3-oxocyclohexancarboxyaldehyde ethylenacetal

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of 3-oxocyclohexancarboxyaldehyde ethylenacetal

There total 2 articles about 3-oxocyclohexancarboxyaldehyde ethylenacetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1,3-DIOXOLANE (646-06-0) + cyclohexenone (930-68-7) → 3-oxocyclohexancarboxyaldehyde ethylenacetal (123762-05-0)

Guidance literature:

With (Bu₄N)₂S₂O₈; at 20 - 25 ℃;

Reference yield:

2-(3-cyclohexenyl)-1,3-dioxolane (28193-08-0) → 3-(1,3-dioxolan-2-yl)-cyclohexanol (32406-86-3) + 4-[1,3]Dioxolan-2-yl-cyclohexanol (123762-03-8) + 4-(1,3-dioxolan-2-yl)cyclohexan-1-one (123762-04-9) + 3-oxocyclohexancarboxyaldehyde ethylenacetal (123762-05-0)

Guidance literature:

With oxygen; isopropyl alcohol; bis(trifluoroacetylacetonato)cobalt(II); at 75 ℃; for 16h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1246/cl.1989.515

upstream raw materials:

2-(3-cyclohexenyl)-1,3-dioxolane

1,3-DIOXOLANE

cyclohexenone

Refernces

• 1、 Manfrotto, Cristina,Mella, Mariella,Freccero, Mauro,Fagnoni, Maurizio,Albini, Angelo. "Photochemical Synthesis of 4-Oxobutanal Acetals and of 2-Hydroxycyclobutanone Ketals". . p. 5024 - 5028. Retrieved 1999.
• 2、 Kim, Yong Hae,Jung, Jae Chul,Choi, Hyun Chul. "FORMATION AND CHARACTERIZATION OF TETRABUTYLAMMONIUM SULFATE RADICAL: APPLICATION TO ORGANIC SYNTHESIS". . p. 431 - 434. Retrieved 2007/10/02.