4'-Methyl-p-dimethylaminoazobenzene

Base Information

• Chemical Name: 4'-Methyl-p-dimethylaminoazobenzene
• CAS No.: 3010-57-9
• Molecular Formula: C15H17 N3
• Molecular Weight: 239.32
• Hs Code.: 2927000090
• European Community (EC) Number: 221-135-3
• NSC Number: 204514
• UNII: 610E3RBW8U
• DSSTox Substance ID: DTXSID801038789
• Nikkaji Number: J30.300C
• Wikidata: Q27263260
• Mol file: 3010-57-9.mol

Synonyms:3010-57-9;4-DIMETHYLAMINO-4'-METHYLAZOBENZENE;4'-Methyl-p-dimethylaminoazobenzene;4-(Dimethylamino)-4'-methylazobenzene;4'-Methyl-4-dimethylaminoazobenzene;N,N-Dimethyl-p-(p-tolylazo)aniline;N,N-Dimethyl-4-(p-tolylazo)aniline;4'-Methyl-4-(dimethylamino)azobenzene;Aniline, N,N-dimethyl-p-(p-tolylazo)-;NSC 204514;N,N-dimethyl-4-[(4-methylphenyl)diazenyl]aniline;N,N-Dimethyl-4-(p-tolyldiazenyl)aniline;p'-Methyl-p-dimethylaminoazobenzene;EINECS 221-135-3;ANILINE, N,N-DIMETHYL-4-(p-TOLYLAZO)-;UNII-610E3RBW8U;Benzenamine, N,N-dimethyl-4-((4-methylphenyl)azo)-;610E3RBW8U;(e)-n,n-dimethyl-4-(p-tolyldiazenyl)aniline;NSC-204514;4-DIMETHYLAMINO-4-METHYLAZOBENZENE;Benzenamine, N,N-dimethyl-4-[(4-methylphenyl)azo]-;p'-Methyl-p-((dimethylamino)azo)benzene;p'-Methyl-p-[(dimethylamino)azo]benzene;81944-73-2;Benzenamine, N,N-dimethyl-4-[2-(4-methylphenyl)diazenyl]-;BENZENAMINE, N,N-DIMETHYL-4-(2-(4-METHYLPHENYL)DIAZENYL)-;NSC204514;SCHEMBL2681312;WLN: 1N1&R DNUNR D1;DTXSID801038789;Aniline,N-dimethyl-p-(p-tolylazo)-;Aniline,N-dimethyl-4-(p-tolylazo)-;MFCD00048015;4-Dimethylamino-4'-methyl-azobenzene;AKOS024302280;4'-(Dimethylamino)-4-methylazobenzene;4'-Methyl-4-[(dimethylamino)azo]benzene;LS-19772;FT-0634600;M0208;METHYL-4-DIMETHYLAMINOAZOBENZENE, 4'-;D91289;4'-METHYL-N,N-DIMETHYL-4-AMINOAZOBENZENE;A820199;Benzenamine,N-dimethyl-4-[(4-methylphenyl)azo]-;N,N-DIMETHYL-4-(4-METHYLPHENYLAZO)ANILINE;Q27263260;N,N-Dimethyl-4-[(E)-(4-methylphenyl)diazenyl]aniline

Chemical Property of 4'-Methyl-p-dimethylaminoazobenzene

Chemical Property:

• Melting Point: 165-167 °C
• Refractive Index: 1.5000 (estimate)
• Boiling Point: 387.4oC at 760 mmHg
• Flash Point: 188.1oC
• PSA: 27.96000
• Density: 1.01g/cm3
• LogP: 4.47640
• Storage Temp.: -20°C Freezer, Under inert atmosphere
• Solubility.: Chloroform (Slightly), Ethyl Acetate (Slightly)
• XLogP3: 4.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 239.142247555
• Heavy Atom Count: 18
• Complexity: 259

Purity/Quality:

97% ^*data from raw suppliers

4-Dimethylamino-4'-methylazobenzene 98% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 40-20/21/22
• Safety Statements: 45-36/37

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)N=NC2=CC=C(C=C2)N(C)C

Technology Process of 4'-Methyl-p-dimethylaminoazobenzene

There total 4 articles about 4'-Methyl-p-dimethylaminoazobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

phenyldiazonium ethyl sulfate + C7H7N2(1+)*C2H5O4S(1-) → N,N-dimethyl-4-(p-tolyldiazenyl)aniline (3010-57-9)

Guidance literature:

In methanol; ethyl acetate; at 20 ℃; for 6h;

DOI:10.1007/BF02496170

Reference yield: 13.0%

N,N-dimethyl-aniline (121-69-7,77733-26-7) + 1,3-di(p-tolyl)triaz-1-ene (785-86-4,813445-46-4) → 4-methyl-2-p-tolylazo-aniline (58010-91-6) + N,N-dimethyl-4-(p-tolyldiazenyl)aniline (3010-57-9)

Guidance literature:

With hydrogenchloride; In ethanol; for 72h;

DOI:10.1246/bcsj.54.2853

Reference yield:

p-toluidine (106-49-0,12221-03-3) + N,N-dimethyl-aniline (121-69-7,77733-26-7) → N,N-dimethyl-4-(p-tolyldiazenyl)aniline (3010-57-9)

Guidance literature:

p-toluidine; With hydrogenchloride; In water; N,N-dimethyl-formamide; for 0.5h;

With sodium nitrite; In water; N,N-dimethyl-formamide; at 0 ℃; for 1h;

N,N-dimethyl-aniline; In water; N,N-dimethyl-formamide; at 0 ℃;

DOI:10.1016/j.dyepig.2015.10.024

upstream raw materials:

N,N-dimethyl-aniline

1,3-di(p-tolyl)triaz-1-ene

p-toluidine

Downstream raw materials:

4-dimethylamino-3-heptafluoropropyl-4'-methylazobenzene

p-toluidine

4-amino-N,N-dimethylaniline

Refernces

• 1、 Zyk,Nesterov,Khlobystov,Zefirov. "Nitrosation of arenes with nitrosonium ethyl sulfate". . p. 506 - 509. Retrieved 2007/10/03.