(Z)-N-(3-(DIMETHYLAMINO)-2-(TRIFLUOROMETHYL)ALLYLIDENE)-N-METHYLMETHANAMINIUM HEXAFLUOROPHOSPHATE

Base Information

• Chemical Name: (Z)-N-(3-(DIMETHYLAMINO)-2-(TRIFLUOROMETHYL)ALLYLIDENE)-N-METHYLMETHANAMINIUM HEXAFLUOROPHOSPHATE
• CAS No.: 292067-84-6
• Molecular Formula: C8H14F9N2P
• Molecular Weight: 351.07
• Mol file: 292067-84-6.mol

Synonyms:(Z)-N-(2-BROMO-3-(DIMETHYLAMINO)ALLYLIDENE)-N-METHYLMETHANAMINIUM HEXAFLUOROPHOSPHATE;

Chemical Property of (Z)-N-(3-(DIMETHYLAMINO)-2-(TRIFLUOROMETHYL)ALLYLIDENE)-N-METHYLMETHANAMINIUM HEXAFLUOROPHOSPHATE

Chemical Property:

• PSA: 19.84000
• LogP: 4.50960

Purity/Quality:

98%,99%, ^*data from raw suppliers

N-[2-Bromo-3-(dimethylamino)-2-propenylidene]-N-methyl-methanaminium hexafluorophosphate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (Z)-N-(3-(DIMETHYLAMINO)-2-(TRIFLUOROMETHYL)ALLYLIDENE)-N-METHYLMETHANAMINIUM HEXAFLUOROPHOSPHATE

There total 1 articles about (Z)-N-(3-(DIMETHYLAMINO)-2-(TRIFLUOROMETHYL)ALLYLIDENE)-N-METHYLMETHANAMINIUM HEXAFLUOROPHOSPHATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N,N,N',N'-tetramethyl-2-bromo-malondialdehyde diimine hydrochloride → N-(2-bromo-3-(dimethylamino)allylidene)-N-methylmethanaminium hexafluorophosphate (291756-78-0,292067-84-6)

Guidance literature:

With hexafluorophosphoric acid; sodium hydroxide; In water; N,N-dimethyl-formamide; at 10 ℃; for 1h;

DOI:10.15227/orgsyn.080.0200

Reference yield: 60.0%

N-(2-bromo-3-(dimethylamino)allylidene)-N-methylmethanaminium hexafluorophosphate (291756-78-0,292067-84-6) + ethyl acetoacetate (141-97-9) → ethyl 5-bromo-2-methyl-pyridine-3-carboxylate (129477-21-0)

Guidance literature:

N-(2-bromo-3-(dimethylamino)allylidene)-N-methylmethanaminium hexafluorophosphate; ethyl acetoacetate; With 1,4-diaza-bicyclo[2.2.2]octane; potassium tert-butylate; In 1,4-dioxane; at -10 ℃; for 5h;

With ammonium acetate; In 1,4-dioxane; at 60 ℃; for 16h; Temperature; Solvent; Reagent/catalyst;

Downstream raw materials:

ethyl 5-bromo-2-methyl-pyridine-3-carboxylate

Refernces