Boronic acid, (6-phenyl-2-naphthalenyl)-

Base Information

• Chemical Name: Boronic acid, (6-phenyl-2-naphthalenyl)-
• CAS No.: 876442-90-9
• Molecular Formula: C16H13BO2
• Molecular Weight: 248.089
• Mol file: 876442-90-9.mol

Synonyms:6-phenylnaphthalene-2-boronic acid;6-phenylnaphthalene-2-yl boronic acid;Boronic acid,(6-phenyl-2-naphthalenyl);2-phenylnaphthalene-6-boronic acid;

Chemical Property of Boronic acid, (6-phenyl-2-naphthalenyl)-

Chemical Property:

• Boiling Point: 478.4±43.0 °C(Predicted)
• PKA: 8.51±0.30(Predicted)
• PSA: 40.46000
• Density: 1.23±0.1 g/cm3 (20 oC 760 Torr)
• LogP: 2.18660
• Storage Temp.: 2-8°C

Purity/Quality:

98%, ^*data from raw suppliers

(6-Phenylnaphthalen-2-yl)boronicacid 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Boronic acid, (6-phenyl-2-naphthalenyl)-

There total 8 articles about Boronic acid, (6-phenyl-2-naphthalenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

4,4,5,5-tetramethyl-2-(2-phenylnaphthyl-6-yl)-1,3,2-dioxaborolane → (6-phenylnaphthalen-2-yl)boronic acid (876442-90-9)

Guidance literature:

4,4,5,5-tetramethyl-2-(2-phenylnaphthyl-6-yl)-1,3,2-dioxaborolane; With sodium periodate; In tetrahydrofuran; water; for 0.5h;

With hydrogenchloride; In tetrahydrofuran; water; at 20 ℃;

Reference yield: 94.0%

2-bromo-6-phenylnaphthalene (22082-94-6) → (6-phenylnaphthalen-2-yl)boronic acid (876442-90-9)

Guidance literature:

6-phenyl-2-bromonaphthalene; With n-butyllithium; In diethyl ether; hexane; toluene; at -40 - -5 ℃; for 1h;

With Triisopropyl borate; In diethyl ether; hexane; toluene; at 20 ℃; for 4h;

With hydrogenchloride; In diethyl ether; hexane; water; toluene;

Reference yield: 94.0%

normal-butyllithium + 2-bromo-6-iodonaphthanlene + boronic acid triisopropyl ester + 2-bromo-6-phenylnaphthalene (22082-94-6) + phenylboronic acid (98-80-6) → (6-phenylnaphthalen-2-yl)boronic acid (876442-90-9)

Guidance literature:

With sodium chloride; In hexane; toluene;

upstream raw materials:

2-bromo-6-phenylnaphthalene

phenylboronic acid

4’-bromo-3-iodo-1,1’-biphenyl

Trimethyl borate

Downstream raw materials:

2-(3-bromophenyl)-6-phenylnaphthalene

10-(6-phenylnaphthalen-2-yl)anthracen

3,5-dimethyl-2-(6-phenylnaphthalen-2-yl)pyrazine

C₄₉H₃₀

Refernces

• 1、 -. "Organometallic Complex, Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device". Page/Page column 40. . Retrieved 2011/10/13.
• 2、 -. "NEW ANTHRACENE DERIVATIVES, PREPARATION METHOD THEREOF AND ORGANIC LIGHT EMITTING DIODE USING THE SAME". Page/Page column 66. . Retrieved 2010/11/28.