Methylmercury acetate

Base Information

• Chemical Name: Methylmercury acetate
• CAS No.: 108-07-6
• Molecular Formula: C3H6 Hg O2
• Molecular Weight: 274.669
• Hs Code.: 2931900090
• European Community (EC) Number: 203-547-5
• DSSTox Substance ID: DTXSID3074286
• NSC Number: 176145
• Wikidata: Q27292145
• Mol file: 108-07-6.mol

Synonyms:Methylmercury acetate;Methyl mercuric acetate;108-07-6;Acetoxymethylmercury;Methylmercuric acetate;(Acetato)methylmercury;acetyloxy(methyl)mercury;Mercury, (acetato-O)methyl-;Mercury, acetoxymethyl-;(Acetato-O)methylmercury;MERCURY, (ACETATO)METHYL-;Caswell No. 573A;CCRIS 7241;EINECS 203-547-5;acetoxy(methyl)mercury;EPA Pesticide Chemical Code 051903;NSC 176145;UNII-W0GUM2OU8K;DTXSID3074286;Mercury, (acetato-kappaO)methyl-;NSC176145;NS00125435;Q27292145

Chemical Property of Methylmercury acetate

Chemical Property:

• Vapor Pressure: 13.9mmHg at 25°C
• Melting Point: 130-142 °C
• Boiling Point: 117.1°Cat760mmHg
• Flash Point: 40°C
• PSA: 26.30000
• Density: g/cm³
• LogP: 0.59510
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 276.007423
• Heavy Atom Count: 6
• Complexity: 52.8

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)O[Hg]C

Technology Process of Methylmercury acetate

There total 21 articles about Methylmercury acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

silver(I) acetate (563-63-3) + methylmercury(II) iodide (143-36-2) → methyl mercury acetate (108-07-6)

Guidance literature:

In ethanol; CH3HgI added to a stirred slurry of CH3COOAg; stirred overnight; filtered; diluted with water; filtered; washed with ethanol; concentrated under reduced pressure at 50-60°C; recrystd. from ethanol;

Reference yield:

mercury(II) diacetate (1600-27-7) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + mercury(I) acetate (631-60-7) + methyl mercury acetate (108-07-6)

Guidance literature:

In methanol; Irradiation (UV/VIS); in absolute methanol;

Reference yield:

mercury(II) diacetate (1600-27-7) + lead(IV) tetraacetate (546-67-8) → lead acetate (301-04-2) + mercury(I) acetate (631-60-7) + methyl mercury acetate (108-07-6)

Guidance literature:

In benzene; heating, filtrate containing a little CH3HgCH3CO2;

upstream raw materials:

mercury(II) diacetate

dimethylmercury

methylmercury(II) iodide

acetic acid

Downstream raw materials:

acetic anhydride

Methylquecksilber-methylmercaptid

acetoxytriethylstannane

β-methylmercury-4-fluorophenylacetylene

Refernces

• 1、 Akagi,Takabatake. "". . p. 761. Retrieved 1974.
• 2、 Plazzogna et al.. "". . p. 500. Retrieved 1969.
• 3、 Sayre,Jensen. "". . p. 4700,4701 - 4703. Retrieved 1978.
• 4、 Bach, Robert D.,Vardhan, Harsha B.,Rahman, A. F. M. Maqsudur,Oliver, John P.. "A 199Hg FT-NMR and X-ray structural study of the interaction of MeHgII with pyridines. The effect of solvent and steric interactions". . p. 846 - 852. Retrieved 2008/10/08.