4-BROMO DIPHENYL SULFIDE

Base Information

• Chemical Name: 4-BROMO DIPHENYL SULFIDE
• CAS No.: 65662-88-6
• Molecular Formula: C12H9BrS
• Molecular Weight: 265.173
• Mol file: 65662-88-6.mol

Synonyms:Sulfide,p-bromophenyl phenyl (7CI);4-Bromodiphenyl sulfide;4-Bromophenyl phenylsulfide;p-Bromophenyl phenyl sulfide;

Chemical Property of 4-BROMO DIPHENYL SULFIDE

Chemical Property:

• Vapor Pressure: 6.35E-05mmHg at 25°C
• Refractive Index: 1.681
• Boiling Point: 355.6 °C at 760 mmHg
• Flash Point: 168.8 °C
• PSA: 25.30000
• Density: 1.49 g/cm³
• LogP: 4.60030

Purity/Quality:

99.5% ^*data from raw suppliers

4-BROMO DIPHENYL SULFIDE 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-BROMO DIPHENYL SULFIDE

There total 62 articles about 4-BROMO DIPHENYL SULFIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1,4-bromoiodobenzene (589-87-7) + thiophenol (108-98-5) → phenyl(4-bromophenyl)sulfide (65662-88-6)

Guidance literature:

With (tris(3,5-dimethyl-1-pyrazolyl)methane)CuI; lithium tert-butoxide; In 1,4-dioxane; at 110 ℃; for 24h; chemoselective reaction; Inert atmosphere;

DOI:10.1021/ic300843a

Reference yield: 97.4%

diphenyl sulfide (139-66-2) → phenyl(4-bromophenyl)sulfide (65662-88-6)

Guidance literature:

With hydrogen bromide; dihydrogen peroxide; In dichloromethane; water; at 25 - 30 ℃; for 3h; Reagent/catalyst;

Reference yield: 96.0%

(C6H5)4SbSC6H4Br*0.12CHCl3 → biphenyl (92-52-4,1594-86-1) + bis(4-bromophenyl)disulfide (5335-84-2) + phenyl(4-bromophenyl)sulfide (65662-88-6) + triphenylantimony (603-36-1) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1)

Guidance literature:

In neat (no solvent); thermal decompn. of Sb compd. in a sealed tube on heating to 140°C for 3 h; not isolated, detected by GLC and TLC;

DOI:10.1016/S0022-328X(00)83047-8

upstream raw materials:

diphenyl sulfide

1,1'-sulfinylbisbenzene

1.4-dibromobenzene

thiophenol

Downstream raw materials:

4,4'-dibromodiphenyl sulfide

1-phenylsulfanyl-4-p-tolylsulfanyl-benzene

(4-chlorophenyl)(4-(phenylthio)phenyl)sulfane

1-phenylsulfanyl-4-o-tolylsulfanyl-benzene

Refernces

• 1、 Adachi, Chihaya,Adler, Florin,Chan, Chin-Yiu,Esser, Birgit,Grenz, David C.,Hermann, Mathias,Rose, Daniel,W?ssner, Jan S.,Wilbuer, Jennifer. "Spiroconjugated Tetraaminospirenes as Donors in Color-Tunable Charge-Transfer Emitters with Donor-Acceptor Structure". supporting information. . Retrieved 2021/12/22.
• 2、 Cao, Han,Liu, Xuejing,Bie, Fusheng,Shi, Yijun,Han, Ying,Yan, Peng,Szostak, Michal,Liu, Chengwei. "Rh(I)-Catalyzed Intramolecular Decarbonylation of Thioesters". . p. 10829 - 10837. Retrieved 2021/07/28.