Boronic acid, (10-[1,1'-biphenyl]-4-yl-9-anthracenyl)-

Base Information

• Chemical Name: Boronic acid, (10-[1,1'-biphenyl]-4-yl-9-anthracenyl)-
• CAS No.: 400607-47-8
• Molecular Formula: C26H19BO2
• Molecular Weight: 374.23900
• Hs Code.: 2931900090
• Mol file: 400607-47-8.mol

Synonyms:(10-[1,1'-biphenyl]-4-yl-9-anthracenyl)boronic acid;;Boronic acid,(10-[1,1'-biphenyl]-4-yl-9-anthracenyl);;B-(10-[1,1'-Biphenyl]-4-yl-9-anthracenyl)boronic acid;;

Chemical Property of Boronic acid, (10-[1,1'-biphenyl]-4-yl-9-anthracenyl)-

Chemical Property:

• Boiling Point: 623 oC
• PKA: 8?+-.0.30(Predicted)
• Flash Point: 331 oC
• PSA: 40.46000
• Density: 1.28
• LogP: 5.00680
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

99.5% ^*data from raw suppliers

(10-([1,1'-Biphenyl]-4-yl)anthracen-9-yl)boronicacid 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Boronic acid, (10-[1,1'-biphenyl]-4-yl-9-anthracenyl)-

There total 2 articles about Boronic acid, (10-[1,1'-biphenyl]-4-yl-9-anthracenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

→ (10-([1,1'-biphenyl]-4-yl)-anthracene-9-yl)boronic acid (400607-47-8)

Guidance literature:

With tert.-butyl lithium; In tetrahydrofuran; at -78 ℃; for 1h;

In tetrahydrofuran; at -78 - 20 ℃; for 3h;

With hydrogenchloride; In tetrahydrofuran; water; at 20 ℃; for 1.5h;

Reference yield: 50.0%

9‐{[1,1'‐biphenyl]‐4‐yl}‐10‐bromoanthracene (400607-05-8) → (10-([1,1'-biphenyl]-4-yl)-anthracene-9-yl)boronic acid (400607-47-8)

Guidance literature:

9‐{[1,1'‐biphenyl]‐4‐yl}‐10‐bromoanthracene; With n-butyllithium; In diethyl ether; hexane; toluene; at -64 ℃; for 2.5h;

In diethyl ether; hexane; toluene; at 20 ℃; for 12.25h;

With hydrogenchloride; water; In diethyl ether; hexane; toluene; at 0 - 10 ℃;

Reference yield: 84.6%

(10-([1,1'-biphenyl]-4-yl)-anthracene-9-yl)boronic acid (400607-47-8) + 2-(4-(4-bromophenyl)-6-(pyrazin-2-yl)pyridin-2-yl)pyrazine (1928706-28-8) → C45H29N5

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In ethanol; toluene; at 90 ℃; for 12h; Inert atmosphere;

upstream raw materials:

9‐{[1,1'‐biphenyl]‐4‐yl}‐10‐bromoanthracene

Refernces

• 1、 -. "POLYCYCLIC COMPOUND AND ORGANIC ELECTRONIC DEVICE COMPRISING SAME". Paragraph 0125-0126; 0127-0128. . Retrieved 2015/06/03.
• 2、 -. "ASYMMETRIC MONOANTHRACENE DERIVATIVE, MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICE AND ORGANIC ELECTROLUMINESCENT DEVICE UTILIZING THE SAME". Page/Page column 36. . Retrieved 2008/06/13.