2-Methylthiopyridine methiodide

Base Information

• Chemical Name: 2-Methylthiopyridine methiodide
• CAS No.: 41681-14-5
• Molecular Formula: C7H10INS
• Molecular Weight: 267.134
• NSC Number: 132333
• DSSTox Substance ID: DTXSID50961899
• Mol file: 41681-14-5.mol

Synonyms:2-Methylthiopyridine methiodide;Pan-W-23;41681-14-5;NSC 132333;Pyridinium, 1-methyl-2-(methylthio)-, iodide;S(C)c1ccccn1C;C7H10NS.I;DTXSID50961899;NSC132333;NSC-132333;LS-132748;1-METHYL-2-(METHYLSULFANYL)PYRIDIN-1-IUM IODIDE

Chemical Property of 2-Methylthiopyridine methiodide

Chemical Property:

• Boiling Point: 237.7°Cat760mmHg
• Flash Point: 97.6°C
• Density: 1.05g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 266.95787
• Heavy Atom Count: 10
• Complexity: 85

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[N+]1=CC=CC=C1SC.[I-]

Technology Process of 2-Methylthiopyridine methiodide

There total 7 articles about 2-Methylthiopyridine methiodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

pyridine-2-thione (2637-34-5,646031-56-3) + methyl iodide (74-88-4) → 1-Methyl-2-(methylthio)pyridinium iodide (41681-14-5)

Guidance literature:

In dichloromethane; for 8h; Ambient temperature;

Reference yield:

1-methyl-2-pyridinethione (2044-27-1) + methyl iodide (74-88-4) → 1-Methyl-2-(methylthio)pyridinium iodide (41681-14-5)

Guidance literature:

With acetone;

Reference yield:

2-methylsulfanyl-pyridine (18438-38-5,79639-75-1) + methyl iodide (74-88-4) → 1-Methyl-2-(methylthio)pyridinium iodide (41681-14-5)

Guidance literature:

With acetone;

DOI:10.1039/jr9510001723

upstream raw materials:

1-methyl-2-pyridinethione

methyl iodide

2-methylsulfanyl-pyridine

pyridine-2-thione

Downstream raw materials:

methylthiol

1-methyl-2-pyridone

1,4-dihydro-1-methyl-2-methylthio-4-(2,6-dioxocyclohexylidene)pyridine

3-ethyl-5-(1-methyl-1H-pyridin-2-ylidene)-2-thioxothiazolidine-4-one

Refernces

• 1、 Peng, Zheng-Hong,Zhou, Xiang-Feng,Carroll, Suzanne,Geise, Herman J.,Peng, Bi-Xian,Dommisse, Roger,Esmans, Eddy,Carleer, Robert. "Structure of rhodanine cyanine dyes, spectroscopy and performance in photographic emulsions". . p. 1325 - 1333. Retrieved 2007/10/03.
• 2、 Singh, Harjit,Batra, M. S.,Singh, Paramjit. "Synthesis of Functionalised Enamines from α-Thioiminium Salts and Active Methylene Compounds". . p. 1176 - 1180. Retrieved 2007/10/02.