9,10-Dicyanoanthracene

Base Information

• Chemical Name: 9,10-Dicyanoanthracene
• CAS No.: 1217-45-4
• Molecular Formula: C16H8N2
• Molecular Weight: 228.253
• Hs Code.: 29269095
• European Community (EC) Number: 679-755-9
• NSC Number: 17556
• DSSTox Substance ID: DTXSID4061628
• Nikkaji Number: J47.160G
• Wikidata: Q27122536
• Metabolomics Workbench ID: 57690
• Mol file: 1217-45-4.mol

Synonyms:9,10-dicyanoanthracene

Chemical Property of 9,10-Dicyanoanthracene

Chemical Property:

• Appearance/Colour: yellow to golden yellow needles or powder
• Vapor Pressure: 1.16E-09mmHg at 25°C
• Melting Point: 340 °C(lit.)
• Refractive Index: 1.73
• Boiling Point: 487.7 °C at 760 mmHg
• Flash Point: 247.8 °C
• PSA: 47.58000
• Density: 1.28 g/cm³
• LogP: 3.73636
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 228.068748264
• Heavy Atom Count: 18
• Complexity: 345

Purity/Quality:

97% ^*data from raw suppliers

DCA ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22
• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C(=C3C=CC=CC3=C2C#N)C#N
• Uses: 9,10-Anthracenedicarbonitrile may be used as photosensitizer to investigate the photoisomerization of trans-stilbene (TS) in sodium dodecyl sulfate (SDS)/benzyl alcohol (BA)/H2O system.

Technology Process of 9,10-Dicyanoanthracene

There total 84 articles about 9,10-Dicyanoanthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Anthracene-9,10-dicarbonitrile; compound with 1,2,3,4,5,6-hexamethyl-benzene (17263-12-6) → 9,10-Dicyanoanthracene (1217-45-4) + Hexamethylbenzene (87-85-4)

Guidance literature:

In acetonitrile; Thermodynamic data; Rate constant; ΔG;

DOI:10.1021/ja00167a027

Reference yield:

Anthracene-9,10-dicarbonitrile; compound with 4,4'-dimethyl-biphenyl → 9,10-Dicyanoanthracene (1217-45-4) + (4,4'-dimethyl-1,1'-biphenyl) (613-33-2)

Guidance literature:

In acetonitrile; Thermodynamic data; Rate constant; ΔG;

DOI:10.1021/ja00167a027

Reference yield:

Anthracene-9,10-dicarbonitrile; compound with 2,6-dimethyl-naphthalene → 9,10-Dicyanoanthracene (1217-45-4) + 2.6-dimethylnaphthalene (581-42-0)

Guidance literature:

In acetonitrile; Thermodynamic data; Rate constant; ΔG;

DOI:10.1021/ja00167a027

upstream raw materials:

C₁₆H₁₄N₄

lead(IV) tetraacetate

Anthracene-9,10-dicarbonitrile; compound with naphthalene

Anthracene-9,10-dicarbonitrile; compound with 2-methyl-naphthalene

Downstream raw materials:

fluorene radical cation

Naphthalene

biphenyl

9,10-phenanthrenequinone

Refernces

• 1、 Zhang, Bao Wen,Kuriyama, Yasunao,Cao, Yi,Tokumaru, Katsumi. "Salt Effect for Accelerating Charge Separation from 9,10-Dicyanoanthracene-Stilbene Exciplex in Dichloromethane". . p. 1859 - 1862. Retrieved 1993.
• 2、 Gl?cklhofer, Florian,Lunzer, Markus,Fr?hlich, Johannes. "Facile synthesis of cyanoarenes from quinones by reductive aromatization of cyanohydrin intermediates". . p. 950 - 952. Retrieved 2015.
• 3、 Gillmore,Neiser,McManus,Roh,Dombrowski,Brown,Dinnocenzo,Farid,Robello. "Quantum amplified isomerization: A new concept for polymeric optical materials". . p. 7684 - 7694. Retrieved 2005.
• 4、 Kim, Hyunwoo,Kim, Hyungjun,Lambert, Tristan H.,Lin, Song. "Reductive Electrophotocatalysis: Merging Electricity and Light to Achieve Extreme Reduction Potentials". supporting information. p. 2087 - 2092. Retrieved 2020/02/04.
• 5、 Estivill, Carla,Mendizabal, Julen,Virgili, Albert,Monteagudo, Eva,Flor, Teresa,Sánchez-Ferrando, Francisco,Alvarez-Larena, Angel,Piniella, Juan F.. "Preparation of (1R,1′R)-1,1′-(anthracene-9,10-diyl)bis(2,2,2-trifluoroethanamine): a chiral diamine with low basicity". body text. p. 171 - 176. Retrieved 2009/04/10.