1-N-PROPYLCYCLOHEXANOL

Base Information

• Chemical Name: 1-N-PROPYLCYCLOHEXANOL
• CAS No.: 5445-24-9
• Molecular Formula: C9H18O
• Molecular Weight: 142.241
• Hs Code.: 2906199090
• Mol file: 5445-24-9.mol

Synonyms:1-Hydroxy-1-propylcyclohexane;1-Propyl-1-cyclohexanol;NSC 21983;

Chemical Property of 1-N-PROPYLCYCLOHEXANOL

Chemical Property:

• Vapor Pressure: 0.116mmHg at 25°C
• Melting Point: 36.9°C (estimate)
• Refractive Index: 1.465
• Boiling Point: 194.4 °C at 760 mmHg
• Flash Point: 76.5 °C
• PSA: 20.23000
• Density: 0.912 g/cm³
• LogP: 2.48170

Purity/Quality:

99% ^*data from raw suppliers

1-N-PROPYLCYCLOHEXANOL 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Intermediates of Liquid Crystals

Technology Process of 1-N-PROPYLCYCLOHEXANOL

There total 8 articles about 1-N-PROPYLCYCLOHEXANOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

1-allyl-1-cyclohexanol (1123-34-8) + acrylic acid (79-10-7) → 1-oxa-spiro[5.5]undecan-2-one (4481-78-1) + 1-n-propyl-1-cyclohexanol (5445-24-9)

Guidance literature:

With hydrogen; platinum(IV) oxide; ruthenium; In dichloromethane; at 20 ℃; under 760.051 Torr;

DOI:10.1021/ol027347m

Reference yield:

1-Hydroperoxy-1-propargyl-cyclohexan (17715-02-5) → 1-n-propyl-1-cyclohexanol (5445-24-9)

Guidance literature:

With hydrogen; palladium; In ethanol;

Reference yield:

prop-2-ynylcyclohexane (17715-00-3) → 1-n-propyl-1-cyclohexanol (5445-24-9)

Guidance literature:

Multi-step reaction with 2 steps

1: O₂

2: H₂ / Pd / ethanol

With hydrogen; oxygen; palladium; In ethanol;

upstream raw materials:

n-propylmagnesium bromide

cyclohexanone

propylmagnesium iodide

butanoic acid ethyl ester

Downstream raw materials:

4-Hydroxy-1-(1-propyl-cyclohexyl)-benzol

propylcyclohexane

Toluene-4-sulfonic acid; compound with 1-methyl-cyclohexylamine

1-Propyl-cyclohexyl-phosphorimidic acid triethyl ester

Refernces

• 1、 Bertz, Steven H.,Gibson, Charles P.,Dabbagh, Gary. "THE PREPARATION OF LITHIUM ORGANOCUPRATES FROM VARIOUS Cu(I) SALTS". . p. 4251 - 4254. Retrieved 2007/10/02.