2,5-Dichloro-1,4-benzoquinone

Base Information

• Chemical Name: 2,5-Dichloro-1,4-benzoquinone
• CAS No.: 615-93-0
• Deprecated CAS: 78844-56-1
• Molecular Formula: C6H2Cl2O2
• Molecular Weight: 176.987
• Hs Code.: 2914700090
• European Community (EC) Number: 210-453-8
• NSC Number: 6251
• DSSTox Substance ID: DTXSID9060657
• Nikkaji Number: J65.481G
• Wikidata: Q69759030
• ChEMBL ID: CHEMBL3311439
• Mol file: 615-93-0.mol

Synonyms:2,5-DCBQ;2,5-dichlorobenzoquinone

Chemical Property of 2,5-Dichloro-1,4-benzoquinone

Chemical Property:

• Appearance/Colour: yellow powder
• Vapor Pressure: 0.0358mmHg at 25°C
• Melting Point: 160-163 °C
• Refractive Index: 1.568
• Boiling Point: 241.5 °C at 760 mmHg
• Flash Point: 98.5 °C
• PSA: 34.14000
• Density: 1.56 g/cm³
• LogP: 1.38360
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility.: soluble in Methanol
• Water Solubility.: Insoluble in water.
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 175.9431847
• Heavy Atom Count: 10
• Complexity: 235

Purity/Quality:

98% ^*data from raw suppliers

2,5-Dichlorocyclohexa-2,5-diene-1,4-dione ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=C(C(=O)C=C(C1=O)Cl)Cl
• Uses: 2,5-Dichloro-1,4-benzoquinone may be used in the following processes:As a starting material in the synthesis of asterriquinone D.As a model to study the utility of a novel photoreactor with LED (light-emitting diode) light source and a fibre-optic CCD (charge-coupled device) spectrophotometer.2,5-dichloro-3,6-bi(3-indolyl)-1,4-hydroquinone synthesis by palladium catalyzed reaction with indole.

Technology Process of 2,5-Dichloro-1,4-benzoquinone

There total 47 articles about 2,5-Dichloro-1,4-benzoquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

2,5-dichloro-1,4-phenylenediamine (20103-09-7) → 2,5-Dichloro-1,4-benzoquinone (615-93-0)

Guidance literature:

With perchloric acid; at 25 ℃; for 0.516667h; Electrochemical reaction;

Reference yield: 76.0%

2,5-dichloro-1,4-hydroquinone (824-69-1) → 2,5-Dichloro-1,4-benzoquinone (615-93-0)

Guidance literature:

With silver(l) oxide; In diethyl ether; for 0.5h;

DOI:10.1021/ja00288a035

Reference yield: 70.0%

p-benzoquinone (106-51-4) → 2,5-Dichloro-1,4-benzoquinone (615-93-0)

Guidance literature:

With chlorine; mercury(II) oxide; In tetrachloromethane; for 0.5h;

DOI:10.1080/00397919408011701

upstream raw materials:

2,5 dichloroaniline

ethanol

2,3,5,6-tetrachlorocyclohexa-2,5-diene-1,4-dione

1,4-dichloro-2,5-dimethoxybenzene

Downstream raw materials:

2,5-dichloro-3,6-diphenyl-[1,4]benzoquinone

phosphoric acid-(2,5-dichloro-4-methoxy-phenyl ester)-dimethyl ester

phosphoric acid-(4-ethoxy-2,5-dichloro-phenyl ester)-diethyl ester

2-chloro-1,4-naphthoquinone

Refernces

• 1、 Kohn,Gurewitsch. "-". . p. 135. Retrieved 1930.
• 2、 Ohzu, Shingo,Ishizuka, Tomoya,Kotani, Hiroaki,Kojima, Takahiko. "Reactivity of a Ru(iii)-hydroxo complex in substrate oxidation in water". supporting information. p. 15018 - 15021. Retrieved 2015/02/19.
• 3、 Webb, Brian N.,Ballinger, Jordan W.,Kim, Eunjung,Belchik, Sara M.,Lam, Ka-Sum,Youn, Buhyun,Nissen, Mark S.,Xun, Luying,Kang, Chulhee. "Characterization of chlorophenol 4-monooxygenase (TftD) and NADH:FAD oxidoreductase (TftC) of burkholderia cepacia AC1100". scheme or table. p. 2014 - 2027. Retrieved 2011/02/22.