Dodecylphenylsilane

Base Information

• Chemical Name: Dodecylphenylsilane
• CAS No.: 18510-28-6
• Molecular Formula: C18H32Si
• Molecular Weight: 276.538
• European Community (EC) Number: 660-346-9
• Nikkaji Number: J3.589.392J
• Mol file: 18510-28-6.mol

Synonyms:Dodecyl-phenyl-silane;Phenyldodecylsilane;DODECYLPHENYLSILANE;AKOS024338742;J3.589.392J

Chemical Property of Dodecylphenylsilane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 12
• Exact Mass: 276.227327555
• Heavy Atom Count: 19
• Complexity: 173

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCCCCCCCCCCC[SiH2]C1=CC=CC=C1

Technology Process of Dodecylphenylsilane

There total 2 articles about Dodecylphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

1-dodecene (112-41-4,25067-08-7,62132-67-6) + phenylsilane (694-53-1) → dodecyl(phenyl)silane (18510-28-6)

Guidance literature:

With nickel(II) chloride hexahydrate; potassium tert-butylate; In tetrahydrofuran; at -30 ℃; for 1h; Schlenk technique; Inert atmosphere; Sealed tube;

DOI:10.1021/acs.orglett.1c00111

Reference yield:

phenylsilane (694-53-1) + laurylmagnesium bromide (15890-72-9) → dodecyl(phenyl)silane (18510-28-6)

Guidance literature:

DOI:10.1021/ja01531a021

Reference yield:

dodecyl(phenyl)silane (18510-28-6) + phenylmagnesium bromide (1589-82-8) → benzyl-dodecyl-phenyl-silane (18762-82-8)

Guidance literature:

DOI:10.1021/ja01531a021

upstream raw materials:

phenylsilane

laurylmagnesium bromide

1-dodecene

Downstream raw materials:

benzyl-dodecyl-phenyl-silane

Refernces

• 1、 Nagata, Tatsuki,Tanaka, Tatsuya,Lin, Xianjin,Kondo, Ryota,Suzuki, Takeyuki,Kanda, Yasuharu,Toyao, Takashi,Shimizu, Ken-ichi,Obora, Yasushi. "N,N-Dimethylformamide-protected Fe2O3 Combined with Pt Nanoparticles: Characterization and Catalysis in Alkene Hydrosilylation". . . Retrieved 2021/11/30.
• 2、 -. "METHOD FOR PRODUCING ORGANIC SILICON COMPOUND USING RUTHENIUM NANOPARTICLE CATALYST". Paragraph 0050; 0063-0064; 0076-0078. . Retrieved 2021/09/01.