5-Hexenoic acid, 6-[2-(1-octenyl)phenyl]-, methyl ester, (Z,Z)-

Base Information

• Chemical Name: 5-Hexenoic acid, 6-[2-(1-octenyl)phenyl]-, methyl ester, (Z,Z)-
• CAS No.: 107586-27-6
• Molecular Formula: C21H30O2
• Molecular Weight: 314.468
• Mol file: 107586-27-6.mol

Synonyms:

Chemical Property of 5-Hexenoic acid, 6-[2-(1-octenyl)phenyl]-, methyl ester, (Z,Z)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5-Hexenoic acid, 6-[2-(1-octenyl)phenyl]-, methyl ester, (Z,Z)-

There total 6 articles about 5-Hexenoic acid, 6-[2-(1-octenyl)phenyl]-, methyl ester, (Z,Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.3%

methyl 6-<2-(oct-1-ynyl)phenyl>hex-5-ynoate (107586-25-4) → (Z)-methyl 6-<2-<(Z)-oct-1-enyl>phenyl>hex-5-enoate (107586-27-6)

Guidance literature:

With pyridine; hydrogen; Pd-BaSO₄;

Reference yield:

2,3-dibromobenzene (583-53-9) → (Z)-methyl 6-<2-<(Z)-oct-1-enyl>phenyl>hex-5-enoate (107586-27-6)

Guidance literature:

Multi-step reaction with 3 steps

1: 73.1 percent / bis(triphenylphosphine)palladium dichloride,copper(I) iodide, triethylamine / 110 °C

2: 32.6 percent / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / tetrahydrofuran / 60 °C

3: 77.3 percent / pyridine, hydrogen / palladium on barium sulphate (5percent)

With pyridine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; hydrogen; triethylamine; Pd-BaSO₄; In tetrahydrofuran;

Reference yield:

n-octyne (629-05-0) → (Z)-methyl 6-<2-<(Z)-oct-1-enyl>phenyl>hex-5-enoate (107586-27-6)

Guidance literature:

Multi-step reaction with 3 steps

1: 73.1 percent / bis(triphenylphosphine)palladium dichloride,copper(I) iodide, triethylamine / 110 °C

2: 32.6 percent / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / tetrahydrofuran / 60 °C

3: 77.3 percent / pyridine, hydrogen / palladium on barium sulphate (5percent)

With pyridine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; hydrogen; triethylamine; Pd-BaSO₄; In tetrahydrofuran;

upstream raw materials:

methyl 6-<2-(oct-1-ynyl)phenyl>hex-5-ynoate

n-octyne

1-bromo-2-oct-1-yn-1-ylbenzene

1-octynylzinc chloride

Downstream raw materials:

(Z)-6-<2-<(Z)-oct-1-enyl>phenyl>hex-5-enoic acid

Refernces