Silver(1+) thiocyanate

Base Information

• Chemical Name: Silver(1+) thiocyanate
• CAS No.: 1701-93-5
• Deprecated CAS: 22842-84-8,858235-52-6
• Molecular Formula: CH N S . Ag
• Molecular Weight: 165.952
• Hs Code.: 2930909090
• European Community (EC) Number: 216-934-9
• NSC Number: 88951
• Wikipedia: Silver thiocyanate
• Mol file: 1701-93-5.mol

Synonyms:Silver thiocyanate;1701-93-5;Silver(1+) thiocyanate;Silver thiocyanate, AgSCN;Silver thiocyanate (AgCNS);Thiocyanic acid, silver(1+) salt;Isothiocyanic acid, silver(1+) salt;NSC-88951;SCHEMBL447612;NSC88951

Chemical Property of Silver(1+) thiocyanate

Chemical Property:

• Vapor Pressure: 4.73mmHg at 25°C
• Melting Point: 63-64℃
• Boiling Point: 146°Cat760mmHg
• Flash Point: 42.1°C
• PSA: 62.59000
• Density: 1.126g/cm³
• LogP: 0.39728
• Sensitive.: Light Sensitive
• Solubility.: H2O: insoluble(lit.)
• Water Solubility.: Very slightly soluble in water. Insoluble in ethanol, acetone, acid. Soluble in NH{4}OH
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 165.88806
• Heavy Atom Count: 4
• Complexity: 31.3

Purity/Quality:

99.9% ^*data from raw suppliers

Silver thiocyanate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn,N
• Statements: 20/21/22-32-50/53-52/53
• Safety Statements: 13-60-61-46-36/37

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(#N)S.[Ag]
• Uses: Silver Thiocyanate is an important reagent in the synthesis of silver nanoplates and nanoparticles.

Technology Process of Silver(1+) thiocyanate

There total 65 articles about Silver(1+) thiocyanate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.43%

potassium thioacyanate (333-20-0) + silver(I) chloride → silver thiocyanate (1701-93-5)

Guidance literature:

In not given; byproducts: Cl(1-); reaction at 12 - 16°C in 0.1 M KSCN solution;;

Reference yield:

3Na(1+)*Ag(1+)*4SCN(1-)=Na3Ag(SCN)4 → sodium thiocyanide (540-72-7) + silver thiocyanate (1701-93-5)

Guidance literature:

With water;

Reference yield:

K(1+)*Ag(SCN)2(1-)=KAg(SCN)2 → potassium thioacyanate (333-20-0) + silver thiocyanate (1701-93-5)

Guidance literature:

With water;

upstream raw materials:

Gold(I)-amminrhodanid

Thiocyanate

silver (I) ion

potassium thioacyanate

Downstream raw materials:

N-allyl isothiocyanate

trimethylsilyl isothiocyanate

benzyl-triisothiocyanato-silane

isothiocyanatosilane

Refernces

• 1、 Leung, Henry,Suffolk, Roger J.,Watts, John D.. "". . p. 289 - 300. Retrieved 1986.
• 2、 Mann, F. G.. "". . . Retrieved 1926.
• 3、 Garrick, F. J.,Wilson, C. L.. "". . . Retrieved 1932.
• 4、 Nakayama, Haruo. "Hydrates of Organic Compounds. VII. The Effect of Anions on the Formation of Clathrate Hydrates of Tetrabutylammonium Salts". . p. 877 - 880. Retrieved 1983.
• 5、 Guo, Guo-Cong,Mak, Thomas C.W.. "Unprecedented μ-1,2,3κS : 4,5κN coordination mode of the thiocyanate anion in two new double salts of silver(I), AgSCN·2AgNO3 and AgSCN·AgClO4". . p. 813 - 814. Retrieved 1999.
• 6、 -. "NOVEL COMPOUND AND EPOXY RESIN COMPOSITION CONTAINING THE SAME". Paragraph 0037. . Retrieved 2016/10/07.