Bis(4-nitrophenyl)peroxyanhydride

Base Information

• Chemical Name: Bis(4-nitrophenyl)peroxyanhydride
• CAS No.: 1712-84-1
• Molecular Formula: C14H8 N2 O8
• Molecular Weight: 332.226
• NSC Number: 142611
• DSSTox Substance ID: DTXSID20301364
• Nikkaji Number: J357.393A
• Wikidata: Q82045151
• Mol file: 1712-84-1.mol

Synonyms:1712-84-1;bis(4-nitrophenyl)peroxyanhydride;NSC142611;p-nitrobenzoyl peroxide;SCHEMBL1436249;DTXSID20301364;NSC-142611

Chemical Property of Bis(4-nitrophenyl)peroxyanhydride

Chemical Property:

• Vapor Pressure: 3.52E-11mmHg at 25°C
• Boiling Point: 526.6°Cat760mmHg
• Flash Point: 239.1°C
• Density: 1.532g/cm³
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 5
• Exact Mass: 332.02806522
• Heavy Atom Count: 24
• Complexity: 450

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1C(=O)OOC(=O)C2=CC=C(C=C2)[N+](=O)[O-])[N+](=O)[O-]

Technology Process of Bis(4-nitrophenyl)peroxyanhydride

There total 5 articles about Bis(4-nitrophenyl)peroxyanhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

4-nitro-benzoyl chloride (122-04-3) → p-nitrobenzoyl peroxide (1712-84-1)

Guidance literature:

4-nitro-benzoyl chloride; With dihydrogen peroxide; In diethyl ether; water; at 0 ℃; for 0.333333h;

With sodium hydroxide; In diethyl ether; water; for 0.333333h;

DOI:10.1021/ja1036644

Reference yield: 31.0%

benzoyl chloride (98-88-4) + 4-nitro-benzoyl chloride (122-04-3) → p-nitrobenzoyl peroxide (1712-84-1) + benzoyl-(4-nitro-benzoyl)-peroxide (2765-19-7)

Guidance literature:

4-nitro-benzoyl chloride; With dihydrogen peroxide; In diethyl ether; water; at 0 ℃; for 0.416667h;

benzoyl chloride; With sodium hydroxide; In diethyl ether; water; at 0 ℃; for 0.416667h;

DOI:10.1021/ja1036644

Reference yield:

4-nitro-benzoic acid (62-23-7) → p-nitrobenzoyl peroxide (1712-84-1)

Guidance literature:

With dihydrogen peroxide; dicyclohexyl-carbodiimide; In diethyl ether;

DOI:10.1021/jo01044a002

upstream raw materials:

4-nitro-benzoyl chloride

N-(4-nitrobenzoyl)imidazole

4-nitro-benzoic acid

benzoyl chloride

Downstream raw materials:

4-nitro-benzoic acid

4-nitroperbenzoic acid

N-benzoyl-N-(4-nitro-benzoyl)-aniline

N-p-nitrobenzoyloxy-N-methyl-2-(o-formyl-phenyl)ethylamine

Refernces

• 1、 Botla, Vinayak,Pilli, Navyasree,Malapaka, Chandrasekharam. "Uncatalyzed, on water oxygenative cleavage of inert C-N bond with concomitant 8,7-amino shift in 8-aminoquinoline derivatives". supporting information. p. 1735 - 1742. Retrieved 2019/04/08.
• 2、 Li, Dengke,Xu, Ning,Zhang, Yicheng,Wang, Lei. "A highly efficient Pd-catalyzed decarboxylative ortho-arylation of amides with aryl acylperoxides". supporting information. p. 14862 - 14865. Retrieved 2014/12/11.