1 10-PHENANTHROLINE-5 6-DIONE 97

Base Information

• Chemical Name: 1 10-PHENANTHROLINE-5 6-DIONE 97
• CAS No.: 27318-90-7
• Molecular Formula: C12H6N2O2
• Molecular Weight: 210.192
• Hs Code.: 29349990
• Mol file: 27318-90-7.mol

Synonyms:1,10-Phenanthroline-5,6-quinone;1,10-Phenanthrolinequinone;5,6-Dioxo-1,10-phenanthroline;BCMH 1-48;NSC346882;

Chemical Property of 1 10-PHENANTHROLINE-5 6-DIONE 97

Chemical Property:

• Appearance/Colour: Yellow Solid, Powder, Crystals, Crystalline Powder and/or Chunks
• Vapor Pressure: 1.66E-08mmHg at 25°C
• Melting Point: 260 °C (dec.)(lit.)
• Refractive Index: 1.677
• Boiling Point: 456.1 °C at 760 mmHg
• PKA: 0.26±0.20(Predicted)
• Flash Point: 229.1 °C
• PSA: 59.92000
• Density: 1.444 g/cm³
• LogP: 1.52260
• Storage Temp.: Sealed in dry,Room Temperature
• Water Solubility.: Insoluble in water.

Purity/Quality:

98%min ^*data from raw suppliers

1,10-Phenanthroline-5,6-dione ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: A Bifunctional quinone oxidant 1,10-Phenanthroline-5,6-dione is a Bifunctional quinone oxidant which, when used in conjunction with Zn2+ catalysts, is used to affect the aerobic oxidation of secondary amines to a variety of value added motifs, including indoles.

Technology Process of 1 10-PHENANTHROLINE-5 6-DIONE 97

There total 20 articles about 1 10-PHENANTHROLINE-5 6-DIONE 97 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

5,6-methylenedioxy-1,10-phenanthroline (113492-23-2) → 1,10-phenanthroline-5,6-dione (27318-90-7)

Guidance literature:

With water; bromine; acetic acid;

DOI:10.1016/S0040-4020(01)00122-3

Reference yield: 85.0%

1,10-phenanthroline hydrate (5144-89-8) → 1,10-phenanthroline-5,6-dione (27318-90-7)

Guidance literature:

With sulfuric acid; nitric acid; potassium bromide; at 5 - 100 ℃; for 6h;

Reference yield: 85.0%

→ 1,10-phenanthroline-5,6-dione (27318-90-7)

Guidance literature:

upstream raw materials:

5-methoxy-1,10-phenanthroline

1,10-Phenanthroline

5-Nitro-1,10-phenanthroline

N-phenyl-1,10-phenanthroline-5,6-quinone monoimine

Downstream raw materials:

7-(4-tert-butylbenzoylamino)dipyrido[3,2-a:2',3'-c]phenazine

N-{3-{3''-[(4,4'-dimethoxytrityl)oxy]-2''-hydroxypropoxy}propyl}dipyrido[3,2-a:2',3'-c]phenazine-11-carboxamide

(9a,13a-dihydro-4,5,9,14-tetraaza-benzo[b]triphenylene-11-yl)phenylmethanone

10,13-dimethoxy-11,12-bis(p-toluenesulfamido)-dipyrido[3,2-a:2',3'-c]phenazine

Refernces

• 1、 Amouyal, Edmond,Homsi, Abdulrazzak,Chambron, Jean-Claude,Sauvage, Jean-Pierre. "Synthesis and Study of a Mixed-ligand Ruthenium(II) Complex in Its Ground and Excited States: Bis(2,2'-bipyridine)(dipyridophenazine-N4N5)ruthenium(II)". . p. 1841 - 1845. Retrieved 1990.
• 2、 Antkowiak,Sobczak. "Solvent effect on the reactivity of 1,10-phenanthroline-5,6-dione towards diazomethane". . p. 2799 - 2805. Retrieved 2001.
• 3、 -. "2'-pyrazol-1H-imidazole [4,5-f][1,10] phenanthroline derivate and preparing method and application thereof". Paragraph 0046; 0050. . Retrieved 2017/05/19.