Aluminium methanolate

Base Information

• Chemical Name: Aluminium methanolate
• CAS No.: 865-31-6
• Molecular Formula: CH4 O . 1/3 Al
• Molecular Weight: 120.084
• European Community (EC) Number: 212-735-6
• Nikkaji Number: J195.128I
• Mol file: 865-31-6.mol

Synonyms:Aluminium methanolate;EINECS 212-735-6;865-31-6;Aluminum methanolate;CH4O.1/3Al;C-H4-O.1/3Al

Chemical Property of Aluminium methanolate

Chemical Property:

• Vapor Pressure: 265mmHg at 25°C
• Boiling Point: 48.1°C at 760 mmHg
• Flash Point: 11.1°C
• PSA: 69.18000
• LogP: 0.47760
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 120.0367076
• Heavy Atom Count: 7
• Complexity: 2

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[O-].C[O-].C[O-].[Al+3]

Technology Process of Aluminium methanolate

There total 5 articles about Aluminium methanolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + lithium aluminium tetrahydride (16853-85-3) + o-(dimesitylboryl)[dimethoxy(methyl)silyl]benzene (1251196-96-9) → o-(dimesitylboryl)(methylsilyl)benzene (1251197-02-0) + aluminum methoxide (865-31-6)

Guidance literature:

With BF₃*OEt₂; In tetrahydrofuran; hexane; (N2); soln. of B compd./THF was added dropwise to suspn. of LiAlH4 (1.1 equiv.) in THF at 0°C over min; stirred at 0°C for 2 h; concd. (vac.); stirred in hexane; BF3*OEt2 (5 equiv.) was added at room temp.; stirred at room temp. for 2 h; evapd. (vac.); heated (75°C, 1 mmHg, overnight); dissolved in hexane; filtered; cooled to -30°C; elem. anal.;

DOI:10.1016/j.jorganchem.2010.06.007

Reference yield: 73.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + lithium aluminium tetrahydride (16853-85-3) + o-(dimesitylboryl)[dimethoxy(phenyl)silyl]benzene (1251196-94-7) → o-(dimesitylboryl)(phenylsilyl)benzene (1251196-99-2) + aluminum methoxide (865-31-6)

Guidance literature:

With BF₃*OEt₂; In tetrahydrofuran; hexane; (N2); soln. of B compd./THF was added dropwise to suspn. of LiAlH4 (1.1 equiv.) in THF at 0°C over 4 min; stirred at room temp. for 3 h; concd. (vac.); stirred in hexane; BF3*OEt2 (5 equiv.) was added at room temp.; stirred at room temp. for 2 h; evapd. (vac.); heated (75°C, 1 mmHg, overnight); dissolved in hexane; filtered; cooled to -30°C; elem. anal.;

DOI:10.1016/j.jorganchem.2010.06.007

Reference yield:

cyclotriboric acid trimethyl ester (102-24-9) + triethylaluminum (97-93-8) → triethyl borane (97-94-9) + aluminum methoxide (865-31-6)

Guidance literature:

byproducts: Al2O3;

DOI:10.1021/ja01527a010

upstream raw materials:

cyclotriboric acid trimethyl ester

triethylaluminum

tetrahydrofuran

lithium aluminium tetrahydride

Downstream raw materials:

Phenylketendimethylacetal-2-d

Refernces

• 1、 -. "Isomerization of isolated double bonds to conjugated double bonds in optionally substituted cyclooctadienes". . . Retrieved 2008/06/13.