AZO-TERT-OCTANE

Base Information

• Chemical Name: AZO-TERT-OCTANE
• CAS No.: 39198-34-0
• Molecular Formula: C16H34N2
• Molecular Weight: 254.459
• Mol file: 39198-34-0.mol

Synonyms:Diazene,bis(1,1,3,3-tetramethylbutyl)- (9CI);1,1,1',1',3,3,3',3'-Octamethyl-1,1'-azobutane;2,2'-Azobis(2,4,4-trimethylpentane);Azo-tert-octane;Di-tert-octyldiazene;VR 110;Bis(2,4,4-trimethylpentan-2-yl)diazene;

Chemical Property of AZO-TERT-OCTANE

Chemical Property:

• Vapor Pressure: 0.00314mmHg at 25°C
• Refractive Index: 1.442
• Boiling Point: 292.793 °C at 760 mmHg
• Flash Point: 122.776 °C
• PSA: 24.72000
• Density: 0.815 g/cm³
• LogP: 5.86820

Purity/Quality:

99% ^*data from raw suppliers

AZO-TERT-OCTANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of AZO-TERT-OCTANE

There total 6 articles about AZO-TERT-OCTANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

N,N'-bis(1,1,3,3-tetramethylbutyl)thiadiaziridine 1,1-dioxide (50780-12-6,40121-15-1) → N,N'-bis(1,1,3,3-tetramethylbutyl)diazene (39198-34-0)

Guidance literature:

With sodium hydroxide; In water; at 80 ℃; for 0.5h;

DOI:10.1021/jo00323a021

Reference yield:

N,N'-bis(1,1,3,3-tetramethylbutyl)sulfamide (6281-65-8) → N,N'-bis(1,1,3,3-tetramethylbutyl)diazene (39198-34-0)

Guidance literature:

Multistep reaction; (i) NaH, pentane, (ii) tBuOCl;

DOI:10.1055/s-1972-21965

Reference yield:

N-chloro-N,N'-bis(1,1,3,3-tetramethylbutyl)sulfamide (76613-31-5) → N,N'-bis(1,1,3,3-tetramethylbutyl)diazene (39198-34-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 82 percent / sodium hydride / tetrahydrofuran / 1.) -30 deg C, 2 h, 2.) 0 deg C, 1 h

2: 90 percent / 6 N NaOH / H₂O / 0.5 h / 80 °C / var. reaction partners, var. conditions

With sodium hydroxide; sodium hydride; In tetrahydrofuran; water;

DOI:10.1021/jo00323a021

upstream raw materials:

tert-Octylamine

bis-(1-chloro-1,3,3-trimethyl-butyl)-diazene

trimethylaluminum

N,N'-bis(1,1,3,3-tetramethylbutyl)sulfamide

Downstream raw materials:

2,2,4-trimethylpentane

Refernces

• 1、 Timberlake, Jack W.,Alender, Jeff,Garner, Archie W.,Hodges, Melvin L.,Oezmeral, Cenan,et al.. "Thiadiaziridine 1,1-Dioxides: Synthesis and Chemistry". . p. 2082 - 2089. Retrieved 2007/10/02.