3-Methylbenzenediazonium

Base Information

• Chemical Name: 3-Methylbenzenediazonium
• CAS No.: 63815-25-8
• Molecular Formula: C7H7N2
• Molecular Weight: 119.146
• DSSTox Substance ID: DTXSID20452840
• Nikkaji Number: J238.199K
• Wikidata: Q82273695
• Mol file: 63815-25-8.mol

Synonyms:3-methylbenzenediazonium;Benzenediazonium, 3-methyl-;63815-25-8;SCHEMBL12088319;DTXSID20452840

Chemical Property of 3-Methylbenzenediazonium

Chemical Property:

• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 119.060923232
• Heavy Atom Count: 9
• Complexity: 133

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC(=CC=C1)[N+]#N

Technology Process of 3-Methylbenzenediazonium

There total 3 articles about 3-Methylbenzenediazonium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-(m-tolyl)-3,3-dimethyltriazen (20241-03-6) → 3-methylbenzene diazonium (63815-25-8) + dimethyl amine (124-40-3)

Guidance literature:

With buffer solution pH 1.2; In ethanol; at 37 ℃; Rate constant; μ=0.178;

DOI:10.1007/BF00773812

Reference yield:

1-amino-3-methylbenzene (108-44-1) → 3-methylbenzene diazonium (63815-25-8)

Guidance literature:

With hydrogenchloride; sodium nitrite; In water; at 5 - 10 ℃;

DOI:10.1021/ja00288a035

Reference yield:

→ 3-methylbenzene diazonium (63815-25-8)

Guidance literature:

m-Methylanilin, HBF4, NaNO2;

DOI:10.1021/jo00424a013

upstream raw materials:

1-amino-3-methylbenzene

1-(m-tolyl)-3,3-dimethyltriazen

Downstream raw materials:

3-(3-m-tolyl-triazenyl)-benzoic acid

2-Methyl-4-m-tolylazo-phenol

2-m-tolylcyclohexa-2,5-diene-1,4-dione

5-[(E)-2-(3-methylphenyl)-1-diazenyl]-2-hydroxybenzoic acid

Refernces

• 1、 Carlson, Brian W.,Miller, Larry L.. "Mechanism of the Oxidation of NADH by Quinones. Energetics of One-Electron and Hydride Routes". . p. 479 - 485. Retrieved 2007/10/02.