Erbium(III) chlorid

Base Information

• Chemical Name: Erbium(III) chlorid
• CAS No.: 10138-41-7
• Molecular Formula: Cl3Er
• Molecular Weight: 273.619
• UNII: 867J5QOF46
• Nikkaji Number: J34.809K
• Mol file: 10138-41-7.mol

Synonyms:Erbium(III) chlorid;Erbium(iii)chloride;ERBIUM(3+) CHLORIDE;ERBIUM CHLORIDE [INCI];ERBIUM TRICHLORIDE (ERCL3);AKOS024256121

Chemical Property of Erbium(III) chlorid

Chemical Property:

• Appearance/Colour: pink crystalline
• Melting Point: 774 °C(lit.)
• Boiling Point: 1500 °C
• Flash Point: 1500°C
• PSA: 0.00000
• Density: 4.1 g/mL at 25 °C(lit.)
• LogP: 2.06850
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 270.836859
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Er+3]

Technology Process of Erbium(III) chlorid

There total 29 articles about Erbium(III) chlorid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

[Er(chloride)2(water)6]Cl → erbium(III) chloride (10138-41-7)

Guidance literature:

In neat (no solvent, solid phase); byproducts: H2O; Schlenk techniques; heating Er compd. under vacuum (1E-3 Torr);

DOI:10.1016/j.poly.2010.02.027

Reference yield: 55.49%

samarium(III) oxide + erbium(III) oxide + potassium chloride + chlorine (7782-50-5) → erbium(III) chloride (10138-41-7) + samarium(III) chloride (10361-82-7)

Guidance literature:

With pyrographite; In gas; byproducts: CO; by chlorination-chem. vapor transport react.; mixt. of Er2O3 and Sm2O3 with carbon and KCl (1:1:6:1 at. ratio) placed in alumina reactor and chlorinated with dry Cl2 (20 cm**3/min) at 800 K for 2 h; gas replace by Ar:Cl2 at 800-1300 K; detn. of separation factor;

DOI:10.1016/j.jallcom.2005.02.104

Reference yield: 43.54%

holmium(III) oxide + erbium(III) oxide + potassium chloride + chlorine (7782-50-5) → erbium(III) chloride (10138-41-7) + holmium(III) chloride (853560-92-6,10138-62-2)

Guidance literature:

With pyrographite; In gas; byproducts: CO; by chlorination-chem. vapor transport react.; mixt. of Er2O3 and Ho2O3 with carbon and KCl (1:1:6:1 at. ratio) placed in alumina reactor and chlorinated with dry Cl2 (20 cm**3/min) at 800 K for 2 h; gas replace by Ar:Cl2 at 800-1300 K; detn. of separation factor;

DOI:10.1016/j.jallcom.2005.02.104

upstream raw materials:

hydrogenchloride

erbium chloride hydrate

ErCl₃*H₂O

chlorine

Refernces

• 1、 Chen, Zhigang,Chen, Huili,Hu, He,Yu, Mengxiao,Li, Fuyou,Zhang, Qiang,Zhou, Zhiguo,Yi, Tao,Huang, Chunhui. "Versatile synthesis strategy for carboxylic acid-functionalized upconverting nanophosphors as biological labels". . p. 3023 - 3029. Retrieved 2008.
• 2、 Fuger, Jean,Morss, Lester. "THERMODYNAMICS OF LANTHANIDE ELEMENTS. PART 2. ENTHALPIES OF FORMATION OF ERBIUM TRICHLORIDE AND OF THE AQUEOUS ERBIUM(3+) ION". . p. 1076 - 1078. Retrieved 1980.
• 3、 Seifert,Sandrock. "Ternary chlorides in the systems NaCl/HoCl3 and NaCl/ErCl3". . p. 1525 - 1528. Retrieved 1997.
• 4、 Buechel, Dorothea,Krok-Kowalski, Jozef,Seifert, Hans-Joachim. "Ternary chlorides in the systems CsCl/ErCl3 and RbCl/ErCl3". . p. 297 - 304. Retrieved 1996.
• 5、 Janicki, Rafal,Starynowicz, Przemyslaw,Mondry, Anna. "Lanthanide carbonates". . p. 3601 - 3616. Retrieved 2011/10/11.
• 6、 G?adysz-P?aska, Agnieszka,Majdan, Marek,Ferenc, Wies?awa,Sarzyński, Jan. "Comparison of covalency in the lanthanide chloride and nitrate complexes based on the adsorption data on zeolite y". . p. 469 - 474. Retrieved 2012/03/22.