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hydrogen cyanide
L-arabinose
A
ethyl L-mannonate
B
L-mannono-1,4-lactone
Conditions | Yield |
---|---|
beim Behandeln des hesrgestellten Nitrils mit Bariumhydroxid in Wasser und Erwaermen des nach dem Ansaeuern erhaltenen Reaktionsprodukts mit Aethanol; |
L-arabinose
L-mannono-1,4-lactone
Conditions | Yield |
---|---|
With barium dihydroxide; hydrogen cyanide; water Erhitzen des Reaktionsprodukts mit Butan-1-ol unter Eindampfen; | |
With barium dihydroxide; hydrogen cyanide; water Erhitzen des Reaktionsprodukts mit Aethanol unter Eindampfen; | |
Multi-step reaction with 2 steps 2: water / durch Eindampfen View Scheme |
L-mannono-1,4-lactone
Conditions | Yield |
---|---|
With water durch Eindampfen; |
L-(+)-arabinose
ethanol
sodium cyanide
A
L-gluconic acid
B
ethyl L-mannonate
C
L-mannono-1,4-lactone
Conditions | Yield |
---|---|
With acetyl chloride 1) H2O, overnight, 2) r.t. to 5 deg C; Yield given. Multistep reaction; |
L-(+)-arabinose
sodium cyanide
A
ethyl L-mannonate
C
L-mannono-1,4-lactone
Conditions | Yield |
---|---|
With ethanol; acetyl chloride 1) H2O, overnight, 2) r.t. to 5 deg C; Yield given. Multistep reaction; |
2,3,5,6-tetra-O-acetyl-D-galactono-1,4-lactone
L-mannono-1,4-lactone
Conditions | Yield |
---|---|
With phosphate buffer; porcine pancreatic lipase for 7h; |
Conditions | Yield |
---|---|
With 1-Phenylbut-1-en-3-one; rhodium hydrido (PEt3)3 complex In N,N-dimethyl-formamide at 60 - 80℃; Yield given. Yields of byproduct given; |
acetone
L-mannono-1,4-lactone
2,3,5,6-di-O-isopropylidene-D-gulono-1,4-lactone
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid at 20℃; Inert atmosphere; | 99% |
With toluene-4-sulfonic acid In dimethoxypropane at 25℃; pH=3; Inert atmosphere; |
L-mannono-1,4-lactone
D-glucitol
Conditions | Yield |
---|---|
With Cu/Cr oxide; hydrogen In ethanol at 170 - 180℃; under 90007.2 Torr; for 10h; | 95% |
acetone
L-mannono-1,4-lactone
(3aR,6S,6aR)-6-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one
Conditions | Yield |
---|---|
sulfuric acid; copper(II) sulfate for 22h; | 94% |
With sulfuric acid; copper(II) sulfate at 20℃; for 24h; | 62% |
Molecular Structure:
Molecular Formula: C6H10O6
Molecular Weight: 178.14
IUPAC Name: 5-(1,2-Dihydroxyethyl)-3,4-dihydroxyoxolan-2-one
Synonyms of L-Mannono-1,4-lactone (CAS NO.22430-23-5): L-Mannonic acid-gamma-lactone
CAS NO: 22430-23-5
Product Categories: 13C & 2H Sugars ; Carbohydrates & Derivatives
Melting point: 153-155 °C
Index of Refraction: 1.625
Molar Refractivity: 35.66 cm3
Molar Volume: 100.8 cm3
Surface Tension: 109.3 dyne/cm
Density: 1.766 g/cm3
Flash Point: 201.5 °C
Enthalpy of Vaporization: 84.17 kJ/mol
Boiling Point: 467.9 °C at 760 mmHg
Vapour Pressure of L-Mannono-1,4-lactone (CAS NO.22430-23-5): 1.01E-10 mmHg at 25°C
WGK Germany of L-Mannono-1,4-lactone (CAS NO.22430-23-5): 3