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L-Mannono-1,4-lactone

  • Name L-Mannono-1,4-lactone
  • EINECS228-678-5
  • CAS No. 22430-23-5
  • Density1.766g/cm3
  • PSA107.22000
  • LogP-3.01320
  • SolubilityN/A
  • Melting Point153-155 ºC
  • FormulaC6H10 O6
  • Boiling Point467.9°Cat760mmHg
  • Molecular Weight178.142
  • Flash Point201.5°C
  • Transport InformationN/A
  • AppearanceN/A
  • Safety
  • Risk CodesN/A
  • Molecular Structure
    Molecular Structure of 22430-23-5 (L-Mannono-1,4-lactone)
  • Hazard SymbolsN/A
  • SynonymsN/A
  • Article Data12

L-Mannono-1,4-lactone Synthetic route

74-90-8

hydrogen cyanide

5328-37-0

L-arabinose

A

152772-66-2

ethyl L-mannonate

B

22430-23-5

L-mannono-1,4-lactone

Conditions
ConditionsYield
beim Behandeln des hesrgestellten Nitrils mit Bariumhydroxid in Wasser und Erwaermen des nach dem Ansaeuern erhaltenen Reaktionsprodukts mit Aethanol;
5328-37-0

L-arabinose

22430-23-5

L-mannono-1,4-lactone

Conditions
ConditionsYield
With barium dihydroxide; hydrogen cyanide; water Erhitzen des Reaktionsprodukts mit Butan-1-ol unter Eindampfen;
With barium dihydroxide; hydrogen cyanide; water Erhitzen des Reaktionsprodukts mit Aethanol unter Eindampfen;
Multi-step reaction with 2 steps
2: water / durch Eindampfen
View Scheme
112241-17-5

2,3,5,6-tetra-O-acetyl-D-galactono-1,4-lactone

22430-23-5

L-mannono-1,4-lactone

Conditions
ConditionsYield
With phosphate buffer; porcine pancreatic lipase for 7h;
50-70-4

D-sorbitol

A

1198-69-2

D-glucono-1,4-lactone

B

22430-23-5

L-mannono-1,4-lactone

Conditions
ConditionsYield
With 1-Phenylbut-1-en-3-one; rhodium hydrido (PEt3)3 complex In N,N-dimethyl-formamide at 60 - 80℃; Yield given. Yields of byproduct given;
67-64-1

acetone

22430-23-5

L-mannono-1,4-lactone

67642-42-6

2,3,5,6-di-O-isopropylidene-D-gulono-1,4-lactone

Conditions
ConditionsYield
With toluene-4-sulfonic acid at 20℃; Inert atmosphere;99%
With toluene-4-sulfonic acid In dimethoxypropane at 25℃; pH=3; Inert atmosphere;
22430-23-5

L-mannono-1,4-lactone

50-70-4

D-glucitol

Conditions
ConditionsYield
With Cu/Cr oxide; hydrogen In ethanol at 170 - 180℃; under 90007.2 Torr; for 10h;95%
67-64-1

acetone

22430-23-5

L-mannono-1,4-lactone

49561-21-9

(3aR,6S,6aR)-6-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one

Conditions
ConditionsYield
sulfuric acid; copper(II) sulfate for 22h;94%
With sulfuric acid; copper(II) sulfate at 20℃; for 24h;62%

L-Mannono-1,4-lactone Chemical Properties

Molecular Structure:

Molecular Formula: C6H10O6
Molecular Weight: 178.14
IUPAC Name: 5-(1,2-Dihydroxyethyl)-3,4-dihydroxyoxolan-2-one
Synonyms of L-Mannono-1,4-lactone (CAS NO.22430-23-5): L-Mannonic acid-gamma-lactone
CAS NO: 22430-23-5
Product Categories: 13C & 2H Sugars ; Carbohydrates & Derivatives
Melting point: 153-155 °C 
Index of Refraction: 1.625
Molar Refractivity: 35.66 cm3
Molar Volume: 100.8 cm3
Surface Tension: 109.3 dyne/cm
Density: 1.766 g/cm3
Flash Point: 201.5 °C
Enthalpy of Vaporization: 84.17 kJ/mol
Boiling Point: 467.9 °C at 760 mmHg
Vapour Pressure of L-Mannono-1,4-lactone (CAS NO.22430-23-5): 1.01E-10 mmHg at 25°C

L-Mannono-1,4-lactone Safety Profile

WGK Germany of L-Mannono-1,4-lactone (CAS NO.22430-23-5): 3

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