Canadian Journal of Chemistry p. 1841 - 1844 (1993)
Update date:2022-08-29
Topics:
Douglas
Campbell
Wigfield
The preparation and alkaline hydrolysis of 18O-methyl 2,2-dimethylpropanoate and 18O-methyl triphenylacetate are reported. From mass spectral analysis of the carboxylic acid products, it is concluded that the former substrate is hydrolyzed exclusively by the B(AC)2 mechanism, whereas the latter substrate proceeds 95% by the B(AC)2 mechanism and 5% by the B(AL)2 mechanism. The balance between these two mechanisms is discussed.
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Doi:10.1016/j.molcatb.2013.02.001
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(2015)Doi:10.1002/aoc.4789
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(1954)Doi:10.1007/BF01900067
(1970)Doi:10.1021/ja01846a021
(1941)