Journal of Physical Chemistry p. 2249 - 2254 (1981)
Update date:2022-08-17
Topics:
Hatakeyama,Shiro
Bandow, Hiroshi
Okuda, Michio
Akimoto, Hajime
The reactions of peroxymethylene (CH2OO) and singlet methylene with H2O were studied in the gas phase by near-UV photolysis of ketene and diazomethane.Peroxymethylene formed in the reaction of CH2(3B1) + O2 + M----> CH2OO + M was found to react with H2(18)O to produce labeled formic acid: CH2OO + H2(18)O ---> HC(18)OOH + H2O.Singlet Methylene was found to react with H2O to form methanol, CH2(1A1) + H2O ---> CH3OH, competing with the reactiom CH2(1A1) + CH2N2 ---> C2H4 + N2.
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