JOURNAL OF
POLYMER SCIENCE
ARTICLE
WWW.POLYMERCHEMISTRY.ORG
19 N. Holten-Andersen, M. J. Harrington, H. Birkedal, B. P. Lee, P.
B. Messersmith, K. Y. Lee, J. H. Waite, Science 2010, 328, 216–220.
the reversible behavior of the anthracene-containing copoly-
mer provide a unique method for tuning thermal and photo-
20 M. Burnworth, L. Tang, J. R. Kumpfer, A. J. Duncan, F. L.
Beyer, G. L. Fiore, S. J. Rowan, Nature 2011, 472, 334–338.
physical properties in
a stimuli-responsive manner. In
addition, the reversible crosslinking system affords “high
performance” materials that self-heal under heating or
photo-irradiation. Future work will describe evaluations of
detailed reversibility including photodimerization and ther-
mal dissociation of anthracene, rheological properties, and
the influence of polymer structure.
21 Q. Wang, J. L. Mynar, M. Yoshida, E. Lee, M. Lee, K. Okuro,
K. Kinbara, T. Aida, Nature 2010, 463, 339–343.
22 G. Jiang, C. Liu, X. Liu, G. Zhang, M. Yang, F. Liu, Macro-
mol. Mater. Eng. 2009, 294, 815–820.
23 S. Burattini, H. M. Colquhoun, J. D. Fox, D. Friedmann, B.
W. Greenland, P. J. Harris, W. Hayes, M. E. Mackay, S. J.
Rowan, Chem. Commun. 2009, 6717–6719.
24 K. Yamauchi, J. R. Lizotte, D. M. Hercules, M. J. Vergne, T.
E. Long, J. Am. Chem. Soc. 2002, 124, 8599–8604.
ACKNOWLEDGMENTS
25 K. Yamauchi, J. R. Lizotte, T. E. Long, Macromolecules 2003,
36, 1083–1088.
The authors would like send our acknowledgement to Prof.
Robert B. Moore and Gregory Fahs at Virginia Tech for SAXS
experiments. We would like to thank Keren Zhang for AFM
observations. We also acknowledge the technical discussions
with Evan Margaretta. Finally, we thank TORAY Industries, Inc.
for their financial support.
26 H. Otsuka, K. Aotani, Y. Higaki, A. Takahara, J. Am. Chem.
Soc. 2003, 125, 4064–4065.
27 Y. Higaki, H. Otsuka, A. Takahara, Macromolecules 2006, 39,
2121–2125.
28 X. Chen, M. A. Dam, K. Ono, A. Mal, H. Shen, S. R. Nutt, K.
Sheran, F. Wudl, Science 295, 1698–1702.
29 R. Gheneim, C. P. Berumen, A. Gandini, Macromolecules
2002, 35, 7246–7253.
REFERENCES AND NOTES
30 C. Zeng, H. Seino, J. Ren, K. Hatanaka, N. Yoshie, Macromo-
lecules 2013, 46, 1794–1802.
€
1 D. Dohler, P. Michael, W. Binder, In Self-healing Polymers:
From Principles to Applications, W. H. Binder, Ed.; Wiley-VCH:
31 Y. L. Liu, T. W. Chuo, Polym. Chem. 2013, 4, 2194–2205.
Weinheim, 2013; Chapter 1, pp 5–45.
ꢀ
32 J. M. Garcıa, G. O. Jones, K. Virwani, B. D. McCloskey, D. J.
2 R. P. Wool, Soft Matter 2008, 4, 400–418.
Boday, G. M. ter Huurne, H. W. Horn, D. J. Coady, A. M.
Bintaleb, A. M. S. Alabdulrahman, F. Alsewailem, H. A. A.
Almegren, J. L. Hedrick, Science 2014, 344, 732–735.
3 S. D. Bergman, F. Wudl, J. Mater. Chem. 2008, 18, 41–62.
4 B. J. Blaiszik, S. L. B. Kramer, S. C. Olugebefola, J. S. Moore,
N. R. Sottos, S. R. White, Annu. Rev. Mater. Res. 2010, 40, 179–
211.
33 M. Coursan, J. P. Desvergne, A. Deffieux, Macromol. Chem.
Phys. 1996, 197, 1599–1608.
34 J. R. Jones, C. L. Liotta, D. M. Collard, D. A. Schiraldi, Mac-
romolecules 1999, 32, 5786–5792.
5 E. B. Murphy, F. Wudl, Prog. Polym. Sci. 2010, 35, 223–251.
6 S. Burattini, B. W. Greenland, D. Chappell, H. M. Colquhoun,
W. Hayes, Chem. Soc. Rev. 2010, 39, 1973–1985.
35 J. Matsui, Y. Ochi, K. Tamaki, Chem. Lett. 2006, 35, 80–81.
36 Z. Shi, W. Liang, J. Luo, S. Huang, B. M. Polishak, X. Li, T.
R. Younkin, B. A. Block, A. K. Y. Jen, Chem. Mater. 2010, 22,
5601–5608.
7 N. K. Guimard, K. K. Oehlenschlaeger, J. W. Zhou, S. Hilf, F.
G. Schmidt, C. Barner-Kowollik, Macromol. Chem. Phys. 2012,
213, 131–143.
37 N. Yoshie, S. Saito, N. Oya, Polymer 2011, 52, 6074–6079.
8 Y. Zhang, A. A. Broekhuis, F. Picchioni, Macromolecules.
2009, 42, 1906–1912.
38 J. D. Tong, C. Zhou, S. Ni, M. A. Winnik, Macromolecules
2001, 34, 696–705.
9 J. A. Syrett, C. Remzi Becer, D. M. Haddleton, Polym. Chem.
2010, 1, 978–987.
39 J. M. Lu, Q. F. Xu, X. Yuan, X. W. Xia, L. H. Wang, J. Polym.
Sci. Part A: Polym. Chem. 2007, 45, 3894–3901.
10 S. H. Cho, S. R. White, P. V. Braun, Adv. Mater. 2009, 21,
645–649.
40 D. Neugebauer, D. Charasim, A. Swinarew, A. Stolarzewicz,
ꢁ
M. Krompiec, H. Janeczek, J. Simokaitiene, J. V. Grazulevicˇius,
11 S. R. White, N. R. Sottos, P. H. Geubelle, J. S. Moore, M. R.
Kessler, S. R. Sriram, E. N. Brown, S. Viswanathan, Nature
2001, 409, 794–797.
Polym. J. 2011, 43, 448–454.
41 M. Demetriou, T. Krasia-Christoforou, J. Polym. Sci. Part A:
Polym. Chem. 2012, 50, 52–60.
12 C. M. Dry, Compos. Struct. 1996, 35, 263–277.
ꢁ
42 M. Stolka, Macromolecules 1975, 8, 8–9.
13 K. S. Toohey, N. R. Sottos, J. A. Lewis, J. S. Moore, S. R.
White, Nat. Mater. 2007, 6, 581–585.
43 D. A. Holden, J. E. Guillet, Macromolecules 1980, 13,
289–295.
ꢀ
14 P. Cordier, F. Tournilhac, C. Soulie-Ziakovic, L. Leibler,
Nature 2008, 451, 977–980.
44 D. Ng, J. E. Guillet, Macromolecules 1982, 15, 724–727.
15 Y. Chen, A. M. Kushner, G. A. Williams, Z. Guan, Nat.
Chem. 2012, 4, 467–472.
45 J. S. Hargreaves, S. E. Webber, Macromolecules 1984, 17,
235–240.
ꢂ
16 L. P. Engle, K. B. Wagener, J. Macrmol. Sci. Rev. Macromol.
Chem. Phys. 1993, C33, 239–257.
46 C. I. Simionescu, M. Grigoras, V. Barboiu, J. Polym. Sci.
Part A: Polym. Chem. 1985, 23, 2089–2098.
17 T. Maeda, H. Otsuka, A. Takahara, Prog. Polym. Sci. 2009,
34, 581–604.
47 C. I. Simionescu, M. Grigoras, G. Onofrei, Makromol. Chem.
1985, 186, 1121–1128.
18 C. J. Kloxin, T. F. Scott, B. J. Adzima, C. N. Bowman, Macro-
molecules 2010, 43, 2643–2653.
48 T. Ishii, Y. Tezuka, S. Kawamoto, T. Uno, J. Photochem.
Photobiol. A Chem. 1994, 83, 55–62.
2310
JOURNAL OF POLYMER SCIENCE, PART A: POLYMER CHEMISTRY 2016, 54, 2302–2311