Edge Article
Chemical Science
networks, incorporating electron-withdrawing (EWG) nitro 13 T. Loiseau, C. Serre, C. Huguenard, G. Fink, F. Taulelle,
groups. Moreover, a bimetallic Al/Fe metal–organic material
containing iron nodes as secondary metallic structural nodes
M. Henry, T. Bataille and G. F ´e rey, Chem.–Eur. J., 2004, 10,
1373–1382.
into the aluminium framework was successfully synthesized, 14 C. Volkringer, H. Leclerc, J. C. Lavalley, T. Loiseau, G. F ´e rey,
and additional redox properties in these MOF-type materials for
M. Daturi and A. Vimont, J. Phys. Chem. C, 2012, 116, 5710–
thiophenol oxidation were conrmed. Denitively, the use of
5719.
functionalized substituted monodentate spacers and the 15 N. Klein, H. C. Hoffmann, A. Cadiau, J. Getzschmann,
cohabitation of metallic nodes with different nature open the
possibilities to generate further families of metal–organic
structures with different topologies, and at the same time it is
M. R. Lohe, S. Paasch, T. Heydenreich, K. Adil,
I. Senkovska, E. Brunner and S. Kaskel, J. Mater. Chem.,
2012, 22, 10303.
also possible to modulate structural defects and vacancy 16 S. J. Garibay and S. M. Cohen, Chem. Commun., 2010, 46,
concentration and, therefore, tune the acid strength of the
hybrid solids.
7700–7702.
17 M. J. Katz, Z. J. Brown, Y. J. Col ´o n, P. W. Siu, K. A. Scheidt,
R. Q. Snurr, J. T. Hupp and O. K. Farha, Chem. Commun.,
2013, 49, 9449.
Conflicts of interest
1
8 B. Zhao, X. Y. Chen, P. Cheng, D. Z. Liao, S. P. Yan and
Z. H. Jiang, J. Am. Chem. Soc., 2004, 126, 15394–15395.
9 A. N. Khlobystov, A. J. Blake, N. R. Champness,
D. A. Lemenovskii, A. G. Majouga, N. V. Zyk and
M. Schr ¨o der, Coord. Chem. Rev., 2001, 222, 155–192.
0 A. Michaelides, M. Aravia, M. G. Siskos and S. Skoulika,
CrystEngComm, 2015, 17, 124.
There are no conicts to declare.
1
Acknowledgements
2
The authors are grateful for nancial support from the Spanish
Government by MAT2014-52085-C2-1-P, MAT2017-82288-C2-1-P
and Severo Ochoa Excellence Program SEV-2016-0683. J. M. M.
acknowledges Predoctoral Fellowships from MINECO for
economical support. The authors thank the MULTY2HYCAT
2
2
1 S. Inoue and S. Fujihara, Inorg. Chem., 2011, 50, 3605–3612.
2 T. R ´o denas, I. Luz, G. Prieto, B. Seoane, H. Miro, A. Corma,
F. Kapteijn, F. X. Llabr ´e s i Xamena and J. Gascon, Nat.
Mater., 2015, 14, 48–55.
(EU-Horizon 2020 funded project under grant agreement no.
2
2
2
3 P. Garc ´ı a-Garc ´ı a, J. M. Moreno, U. D ´ı az, M. Bruix and
A. Corma, Nat. Commun., 2016, 7, 10835.
4 J. M. Moreno, I. Navarro, U. D ´ı az, J. Primo and A. Corma,
Angew. Chem., 2016, 55, 11026–11030.
5 K. Schlichte, T. Kratzke and S. Kaskel, Microporous
Mesoporous Mater., 2004, 73, 81–88.
720783). The European Union is also acknowledged by ERC-
AdG-2014-671093-SynCatMatch.
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