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as stable heterogeneous catalysts. We have found that (1)
Fe(TBaminP)OAc@PAC is the best among other homoge-
nous and heterogeneous Fe and Mn porphyrin catalysts for
alkene epoxidation with NaIO4;(2) acetonitrile/water (2:1,
v/v) has been found to be the best solvent for reaction per-
formed in the presence of the Fe(TBaminP)OAc@PAC, (3)
nitrogen donor axial ligands (i.e., imidazole) can greatly
enhance the catalytic activity of the metalloporphyrin, (4)
only a 0.005 mmol of the Fe(TBaminP)OAc@PAC cata-
lyst was taken to achieve the epoxidation reactions and
the optimal molar ratio of the catalyst, imidazole, alkene
and NaIO4 was 1:5: 60:65, respectively, which applied for
alkene epoxidation at room temperature, (5) the epoxida-
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ity for epoxide, and (6) the catalyst is reusable and can be
applied at least for four times without any significant loss
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Acknowledgments The authors express their appreciation to Yasouj
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