Chemistry of Heterocyclic Compounds p. 347 - 350 (1998)
Update date:2022-08-17
Topics:
Tkachenko
Pushin
Sokolov
Fedoseev
Martynov
A convenient method is proposed for obtaining difficultly available derivatives of 2-amino-5-chloromethyl-2-thiazoline by the cyclization of N-allylthioureas under the action of α-chloronitrosoalkanes. It is assumed that the reaction proceeds as a halogenophilic process leading to the intermediate formamidinesulfenyl chloride which is rapidly and selectively cyclized with the formation of 2-amino-2-thiazoline derivatives. 1998 Plenum Publishing Corporation.
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