Journal of Organic Chemistry p. 808 - 810 (1988)
Update date:2022-08-11
Topics:
Osowska-Pacewicka, Krystyna
Alper, Howard
Monocyclic ketones react with oxygen, potassium hydroxide, potassium carbonate, and catalytic amounts of rhenium carbonyl and polyethylene glycol (PEG-400 or R4H+X- or TDA-1), at room temperature and 1 atm, to give diacids in fine yields.Bicyclic ketones afford keto diacids or hydroxyquinones, depending on the nature of the substrate.
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