Inorganica Chimica Acta p. 174 - 179 (2019)
Update date:2022-08-17
Topics:
Farahmand, Shohreh
Ghiaci, Mehran
Razavizadeh, Jala.S.
The liquid-phase oxidation of benzene to phenol over copper phthalocyanine as a heterogeneous catalyst was studied at room temperature. Acetonitrile was chosen as the preferred solvent and hydrogen peroxide as an eco-friendly oxidant. The yield and selectivity of 13.9% and 100% were obtained, respectively. The catalyst was characterized by FT-IR, UV-Vis, XRD, TGA, XPS, 1H NMR, 13C NMR, CHN, BET, FE-SEM, TEM, and EDX analysis. The effects of different parameters on the catalytic performance of CuPc were also investigated. The reusability of the catalyst was studied, and the results showed that after five cycles the yield of phenol did not change noticeably, probably due to its stability in the reaction conditions.
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