Paper
Dalton Transactions
which well explains the enhanced catalytic performance of
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Conclusions
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In summary, we have successfully synthesized a MOF photo-
catalyst by incorporating Fe(bpy)Cl using PSM, which shows
an enhanced light-absorbing ability and undergoes highly
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S. Habisreutinger, L. Schmidt-Mende and J. Stolarczyk,
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efficient CO
visible-light irradiation. Using transient absorption spec-
troscopy, we show that Fe(bpy)Cl in UiO-68-NH has longer-
2
reduction to form CO with 100% selectivity under
3
2
lived ES and slower recovery of GSB, which is beneficial for
boosting the efficiency of photocatalytic CO production. In
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the photocatalyst (UiO-68-Fe-bpy), enabling at least three
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photocatalysis.
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Conflicts of interest
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There are no conflicts to declare.
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We gratefully acknowledge the National Basic Research
Program of China (grant no. 2017YFA0303504) for financial
support of this work. This work was also supported by a
Project Funded by the Priority Academic Program
Development of Jiangsu Higher Education Institutions. The
use of the Advanced Photon Source at Argonne National
Laboratory was supported by the U. S. Department of Energy,
Office of Science, Office of Basic Energy Sciences, under Award
No. DE-AC02-06CH11357. S. Y. acknowledges the John J. Eisch
fellowship during the 2018–2019 academic year.
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