Tetrahedron Letters p. 6367 - 6370 (1997)
Update date:2022-08-17
Topics:
Wolfe, John P.
Ahman, Jens
Sadighi, Joseph P.
Singer, Robert A.
Buchwald, Stephen L.
Commercially available benzophenone imine serves as a convenient ammonia equivalent in the palladium-catalyzed amination of aryl halides and triflates. The benzophenone imine adducts can be cleaved directly to the corresponding primary anilines by catalytic hydrogenation or treatment with hydroxylamine hydrochloride or a catalytic amount of HCl in wet THF.
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