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FeBrL4 (4b)
The complex was synthesized according to the method described
for 1b using proligand H2L4. Anal. Calcd for C27H39BrFeNO3:
C, 57.77; H, 7.00; N, 2.50. Found C, 57.92; H, 7.02; N, 2.55.
MS (MALDI-TOF) m/z (%, ion): 560.15 (20, [M]+), 481.23
(100, [M − Br]+). UV-vis (solvent) λmax, nm (ε): (methanol) 592
(3680), 331 (5000); (acetonitrile) 515 (4200), 400 (5000); (THF)
566 (4000), 339 (5800); (toluene) 517 (4500), 406 (5900). μeff
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This research was supported by the Natural Sciences and Engi-
neering Research Council (NSERC) of Canada (Discovery and
Research Tools and Instruments Grants to C.M.K., D.B.L. and
H.-B.K., Postgraduate Scholarship to R.K.D, Undergraduate
Student Research Award to P.K.) the Canada Foundation for Inno-
vation (Leaders Opportunity Fund to C.M.K.) and the Provincial
Government of Newfoundland and Labrador (RDC/IRIF grants to
C.M.K). K.H. thanks Memorial University of Newfoundland
School of Graduate Studies for funding. P.K. thanks the Inorganic
Chemistry Exchange (ICE) program of the Chemical Institute of
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Dalton Trans., 2012, 41, 4806–4816 | 4815