Journal of Physical Chemistry p. 9665 - 9675 (1994)
Update date:2022-08-11
Topics:
Lim, S. K.
Burba, M. E.
Albrecht, A. C.
The mobilities of several radical cations and anions are measured in n-hexane using a thin-sheet time-of-flight (TOF) technique.We observe the radical cations of N,N,N',N'-tetramethyl-p-phenylenediamine, zinc tetraphenylporphine, and pyrene and the radical anions of perfluorobenzene, p-benzoquinone, anthraquinone, chloranil, buckminsterfullerene (C60), and octafluoronaphthalene.For all electron acceptors but C60, the dependence of the anionic TOF on acceptor concentration reveals the appearance of the homodimer radical anion at sufficiently high concentrations.The equilibrium constant for the monomer anion/monomer acceptor association reaction is obtained from the concentration studies.A Born-Haber cycle is then applied to estimate the difference between the electron affinities of the monomer and dimer molecules in the gas phase.
View MoreXiamen Kaijia Imp & Exp Co., Ltd.
Contact:86-592-5101177
Address:Room406 Luhui Building No. 65 Haitian Road Huli Xiamen,China.
Shanghai Micro-mega Industry Co., Ltd.
Contact:0086-21-34628682;57153848
Address:Rm413,No.413,West Meilong Road, Minhang District,Shanghai P R China
Beijing Hope Pharmaceutical Co., Ltd.
Contact:86-10-67886402
Address:309,Block 1 District B,No.12 Hongda North Road , Beijing Economic-Technological Development Area, Beijing, China
Jiangsu Jiuri Chemical Co.,Ltd.
Contact:+86-519-82118868
Address:Tianwang Town, Jurong City, Jiangsu Province, China
Zibo XiWeiLi Spice Limited Company
Contact:86-533-7220051
Address:Shandong province Zibo city Linzi Qilu Chemical Industrial Park South of ethylene, , China
Doi:10.1002/(SICI)1099-0690(199802)1998:2<253::AID-EJOC253>3.0.CO;2-E
(1998)Doi:10.1039/c7ta08061a
(2017)Doi:10.1016/j.tet.2007.03.049
(2007)Doi:10.1021/jo00829a075
(1970)Doi:10.1039/c6nj03450k
(2017)Doi:10.1007/s10600-005-0203-y
(2005)