Journal of Physical Chemistry p. 1205 - 1209 (1984)
Update date:2022-08-30
Topics:
Grodkowski, J.
Neta, P.
One-electron oxidation of phenol, p-methoxyphenol, N,N,N',N'-tetramethyl-p-phenylenediamine, chlorpromazine, and zinc tetraphenylporphyrin was studied by pulse radiolysis in carbon tetrachloride solutions.Phenols form phenoxyl radicals and the other compounds form cation radicals with yields strongly dependent on solute concentration.The highest yield in deoxygenated solutions approached G = 4.In the presence of oxygen an additional oxidation step is observed owing to CCl3O2. radicals and the overall oxidation yield approached G = 8.ZnTPP was found to be oxidized to the cation radical without any side effects, unlike oxidation in 1,2-dichloroethane which was accompanied by demetallation owing to HCl production.
View Morewebsite:http://www.sjzthld.com
Contact:86-311-66699812
Address:NO.600 ZHONGSHAN EAST ROAD SHIJIAZHUANG
Valiant Fine Chemicals Co., Ltd.
Contact:+86 535 6101878/6374484
Address:11 Wuzhishan Rd.,YTETDZ,Yantai,264006,Shandong,China
Contact:18669908765
Address:Zibo City, Shandong Province, P.R.China
MedicalChem(Yancheng)Manuf.Co.,Ltd.
Contact:+86-515-84383366
Address:Touzeng BinHai, YanCheng City, JiangSu Province, China
Ningbo Hi-tech Zone Nice-Synth Chemical Industry Ltd.
Contact:+86-(574)-81110986
Address:No. 1210, Building 3, Wante Business Centre, Hi-tech Zone, Ningbo
Doi:10.1016/S0008-6215(99)00213-X
(1999)Doi:10.1021/jp990884c
(2000)Doi:10.1002/zaac.201600231
(2016)Doi:10.1107/S0108270110044884
(2010)Doi:10.1021/bc900545h
(2010)Doi:10.1139/v68-071
(1968)