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D. L. Boger et al./Bioorg. Med. Chem. 6 (1998) 1347±1378
17, A2B4C2: 1H NMR (CDCl3, 500 MHz) d 7.06 (m,
8H), 6.77 (m, 8H), 6.54 (m, 8H), 4.37±3.84 (m, 18H),
3.83±3.67 (m, 64H), 3.42 (br s, 8H), 2.70 (br s, 8H); IR
1423, 1329, 1303, 1245, 1126, 1031, 999, 965, 821,
735 cm 1; MALDI±FTMS (NBA±NaI) m/z 2133.9620
(M+Na+, C108H138N14O30 requires 2133.9601).
(®lm) Vmax 3274, 3067, 2937, 2836, 1659, 1592, 1512,
1
1462, 1423, 1328, 1244, 1193, 1126, 1032, 966, 822 cm
;
17, A2B4C9: 1H NMR (CDCl3, 500 MHz) d 7.06 (m,
8H), 6.78 (m, 8H), 6.51 (m, 8H), 4.33 (m, 8H), 4.12±3.67
(m, 72H), 3.40 (m, 8H), 2.72 (m, 8H), 2.50±1.20 (m,
10H); IR (®lm) Vmax 3266, 3074, 2939, 2827, 1656, 1592,
1512, 1462, 1423, 1328, 1300, 1245, 1126, 1030, 964,
844 cm 1; MALDI±FTMS (NBA±NaI) m/z 2133.9516
(M+Na+, C108H138N14O30 requires 2133.9601).
MALDI±FTMS (NBA±NaI) m/z 2077.8980 (M+Na+,
C104H130N14O30 requires 2077.8975).
1
17, A2B4C3: H NMR (CDCl3, 500 MHz) d 7.07 (br s,
8H), 6.78 (m, 8H), 6.52 (m, 8H), 4.32 (br s, 8H), 4.16±
3.69 (m, 74H), 3.41 (br s, 8H), 2.72 (m, 8H), 2.42 (s,
4H); IR (®lm) Vmax 3279, 3062, 2932, 2832, 1652, 1593,
1557, 1512, 1463, 1423, 1329, 1298, 1244, 1183, 1126,
1028, 1004, 969, 824 cm 1; MALDI±FTMS (NBA±NaI)
m/z 2105.9273 (M+Na+, C106H134N14O30 requires
2105.9287).
1
17, A2B4C10: H NMR (CDCl3, 500 MHz) d 7.08 (m,
8H), 6.79 (m, 8H), 6.52 (m, 8H), 4.32 (m, 8H), 4.17±3.68
(m, 72H), 3.41 (m, 8H), 2.70 (m, 8H), 2.50±1.20 (m,
10H); IR (®lm) Vmax 3272, 3073, 2938, 2827, 1651, 1593,
1557, 1512, 1463, 1423, 1329, 1301, 1245, 1182, 1126,
1031, 1003, 964, 823, 733 cm 1; MALDI±FTMS (NBA±
NaI) m/z 2133.9574 (M+Na+, C108H138N14O30
requires 2133.9601).
1
17, A2B4C4: H NMR (CDCl3, 500 MHz) d 8.60±7.20
(m, 4H), 7.06 (br s, 8H), 6.67 (m, 8H), 6.54 (m, 8H), 4.32
(m, 8H), 4.12±3.69 (m, 72H), 3.40 (m, 8H), 2.72 (m, 8H);
IR (®lm) Vmax 3268, 3076, 2936, 2838, 1651, 1592, 1557,
1512, 1462, 1423, 1329, 1298, 1244, 1178, 1125, 1031,
999, 964, 822 cm 1; MALDI±FTMS (NBA±NaI) m/z
17, A2B4C41: 1H NMR (CDCl3, 500 MHz) d 7.02 (br s,
8H), 6.75 (br s, 8H), 6.52 (br s, 8H), 4.30 (br s, 8H),
4.10±3.70 (m, 72H), 3.40 (br s, 8H), 2.71 (br s, 8H), 2.02
2127.9107
2127.9131).
(M+Na+,
C108H132N14O30
requires
(br s, 8H); IR (®lm) Vmax 3270, 3077, 2936, 1658, 1592,
1
1512, 1461, 1423, 1329, 1245, 1126, 1033, 964, 733 cm
;
1
17, A2B4C5: H NMR (CDCl3, 500 MHz) d 8.31±7.20
(m, 4H), 7.08 (m, 8H), 6.78 (m, 8H), 6.54 (m, 8H), 4.32
(br s, 8H), 4.12±3.68 (m, 72H), 3.38 (m, 8H), 2.72 (m,
8H); IR (®lm) Vmax 3266, 3067, 2939, 2828, 1652, 1592,
1557, 1512, 1461, 1423, 1328, 1298, 1244, 1183, 1126,
1024, 1003, 959, 821 cm 1; MALDI±FTMS (NBA±NaI)
m/z 2127.9062 (M+Na+, C108H132N14O30 requires
2127.9131).
FABHRMS (NBA±CsI) m/z 2246.8790 (M+Cs++13C,
C
107H136N14O31 requires 2246.8584).
17, A2B4C42: 1H NMR (CDCl3, 500 MHz) d 7.02 (br s,
8H), 6.75 (br s, 8H), 6.52 (br s, 8H), 4.30 (br s, 8H),
4.10±3.70 (m, 72H), 3.40 (br s, 8H), 2.71 (br s, 8H), 2.02
(m, 8H), 1.60 (br s, 4H); IR (®lm) Vmax 3270, 3075,
2937, 1658, 1592, 1512, 1462, 1422, 1328, 1244, 1181,
1126, 1033, 823, 734 cm 1; FABHRMS (NBA±CsI) m/
1
17, A2B4C6: H NMR (CDCl3, 500 MHz) d 8.10±7.20
z
2274.9110 (M+Cs++13C, C109H140N14O31 requires
2274.8897).
(m, 6H), 7.05 (m, 8H), 6.79 (m, 8H), 6.51 (m, 8H), 4.30
(br s, 8H), 4.08±3.68 (m, 72H), 3.40 (m, 8H), 2.72 (m,
8H); IR (®lm) Vmax 3273, 3074, 2937, 2837, 1655, 1593,
17, A2B4C44: 1H NMR (CDCl3, 500 MHz) d 7.02 (br s,
8H), 6.75 (br s, 8H), 6.52 (br s, 8H), 4.30 (br s, 8H),
4.10±3.70 (m, 80H), 3.40 (br s, 8H), 2.71 (br s, 8H); IR
(®lm) Vmax 3270, 3069, 2937, 2837, 1657, 1592, 1512,
1512, 1463, 1423, 1328, 1298, 1244, 1195, 1126, 1030, 1009,
1
964, 826 cm
;
MALDI±FTMS (NBA±NaI) m/z
2181.9350 (M+Na+, C112H134N14O30 requires 2181.9600).
1461, 1423, 1328, 1244, 1182, 1126, 1032, 964, 823,
1
17, A2B4C7: 1H NMR (CDCl3, 500 MHz) d 7.08 (m,
8H), 6.79 (m, 8H), 6.52 (m, 8H), 4.33 (br s, 8H), 4.08±
3.69 (m, 72H), 3.42 (m, 8H), 2.72 (m, 8H), 2.50±1.20 (m,
10H); IR (®lm) Vmax 3277, 3076, 2935, 2838, 1652, 1592,
1557, 1512, 1463, 1423, 1328, 1298, 1244, 1178, 1126,
1033, 959, 869, 822 cm 1; MALDI±FTMS (NBA±NaI)
m/z 2133.9500 (M+Na+, C108H138N14O30 requires
2133.9601).
733 cm
;
FABHRMS (NBA±CsI) m/z 2249.8351
(M+Cs+, C106H136N14O32 requires 2249.8499).
17, A2B4C45: 1H NMR (CDCl3, 500 MHz) d 7.02 (br s,
8H), 6.75 (br s, 8H), 6.52 (br s, 8H), 4.30 (br s, 8H),
4.10±3.70 (m, 84H), 3.40 (br s, 8H), 2.71 (br s, 8H); IR
(®lm) Vmax 3291, 2938, 1659, 1592, 1512, 1462, 1423,
1328, 1244, 1126, 845 cm 1; FABHRMS (NBA±CsI)
m/z 2293.8973 (M+Cs+, C108H140N14O33 requires
2293.8762).
17, A2B4C8: 1H NMR (CDCl3, 500 MHz) d 7.07 (m,
8H), 6.79 (m, 8H), 6.53 (m, 8H), 4.32 (m, 8H), 4.12±3.69
(m, 72H), 3.40 (m, 8H), 2.73 (m, 8H), 2.50±1.20 (m,
10H); IR (®lm) Vmax 3275, 2938, 1654, 1593, 1512, 1451,
17, A2B4C46: 1H NMR (CDCl3, 500 MHz) d 7.01 (br s,
8H), 6.78 (br s, 8H), 6.51 (br s, 8H), 4.30 (br s, 8H),