Journal of Organic Chemistry p. 6914 - 6920 (1992)
Update date:2022-08-05
Topics:
Vernier, Jean-Michel
Hegedus, Louis S.
Miller, David B.
Photolysis of <(amino)(aryl)carbene>chromium complexes having the optically active amino alcohol (1R,2S)-(-)- or (1S,2R)-(+)-2-amino-1,2-diphenylethanol as the amino group produced aryl-substituted oxazinones in good yield with reasonable diastereoselectivity.Facile separation of diastereoisomers followed by mild reductive cleavage produced several arylglycines, having either electron-donating or withdrawing groups on the aromatic ring, in good overall yield and with excellent enantiomeric excess.
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