Tetrahedron Asymmetry p. 567 - 572 (1992)
Update date:2022-08-04
Topics:
Cativiela
Diaz-de-Villegas
Galvez
The trisubstituted olefinic bond of chiral cyclic α,β-didehydroamino acid derivatives was hydrogenated in the presence of Pd/C with >95% diastereoface discrimination to give, after hydrolysis, the corresponding S-amino acids. The reduction of the double bond with L-selectride does not change the orientation of diastereoface discrimination and the diastereoselectivity is still high.
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Doi:10.1016/S0040-4039(00)79067-8
(1992)Doi:10.3390/molecules25040769
(2020)Doi:10.1002/cctc.201200435
(2013)Doi:10.1016/j.tetlet.2012.11.110
(2013)Doi:10.1002/asia.201200859
(2013)Doi:10.1016/j.tetlet.2012.11.079
(2013)