Journal of Organometallic Chemistry p. 17 - 32 (1989)
Update date:2022-08-04
Topics:
Diemert, K.
Kuchen, W.
Lorenzen, D.
Aminophosphines RP(NR'2)2 (R = Ph, cyclo-Hex, (-)-Men, t-Bu; R' = Me, Et) as ligands L in complexes (CO)5ML (M = Cr, Mo, W) have been found to react with HX (X = Cl, Br) mainly under substitution of only one of the two dialkylamino groups by halogen.Under similar conditions the free phosphines are converted into the dihalogenphosphines.The halogenamino complexes (CO)5MPRXNR'2 are readily accessible by this reaction, the mechanism of which is discussed.The preparation of several new compounds RP(NR'2)2 is reported.
View MoreContact:13120882795;+86-21-34621078;+86-021-31122318
Address:Suite 2,No.2715 Longwu Road
Contact:
Address:ROOM 1715, No#345 Jin Xiang Road, Pudong District
Nanjing Chemical Material Corp.(NCMC)
website:http://www.njchemm.com
Contact:0086-25-83172879
Address:B12 Technology and Innovation Building, Nanjing Tech University, No.5 New Model Road
Zhejiang Golden-Shell Pharmaceutical Co.,Ltd.
Contact:+86-576-87501888 / 87501988
Address:No.89 Zhongxing Road. Li'ao, Yuhuan, Zhejiang, China
Jiangxi Dongbang Pharmaceutical Co., Ltd.
Contact:+86-795-4433603, 4433388
Address:Fengxin Industrial Park, Fengxin County, Jiangxi Province, P.R.C
Doi:10.1080/15533174.2011.610018
(2012)Doi:10.1016/j.tetlet.2010.10.085
(2011)Doi:10.1002/adsc.201000666
(2010)Doi:10.1016/j.tet.2010.11.048
(2011)Doi:10.1248/cpb.37.2209
(1989)Doi:10.1021/om100804k
(2011)