16292-17-4

Basic information

• Product Name: BIS(4-BROMOPHENYL)AMINE
• Synonyms: 4,4'-DIBROMODIPHENYLAMINE;BIS(4-BROMOPHENYL)AMINE;4,4μ-Dibromodiphenylamine, N-phenyl-4,4μ-dibromoaniline;N-phenyl-4,4μ-dibromoaniline;Bis(4-bromophenyl)amine,4,4′-Dibromodiphenylamine, N-phenyl-4,4′-dibromoaniline;BenzenaMine,4-broMo-N-(4-broMophenyl)-;Double(4-BroMophenyl)aMine;Bis(p-bromophenyl)amine
• CAS NO: 16292-17-4
• Molecular Formula: C₁₂H₉Br₂N
• Molecular Weight: 327.01
• EINECS: 1312995-182-4
• Mol File: 16292-17-4.mol
• Article Data: 49

Chemical Properties

• Melting Point: 106 °C
• Boiling Point: 380.5 °C at 760 mmHg
• Flash Point: 183.9 °C
• Appearance: /
• Density: 1.74 g/cm³
• Vapor Pressure: 5.42E-06mmHg at 25°C
• Refractive Index: 1.68
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Solubility: soluble in Methanol
• PKA: -0.55±0.40(Predicted)
• CAS DataBase Reference: BIS(4-BROMOPHENYL)AMINE(CAS DataBase Reference)
• NIST Chemistry Reference: BIS(4-BROMOPHENYL)AMINE(16292-17-4)
• EPA Substance Registry System: BIS(4-BROMOPHENYL)AMINE(16292-17-4)

Safety Data

• Hazard Codes: Xn
• Statements: 22-41
• Safety Statements: 26-36/39
• WGK Germany: 3
• Hazardous Substances Data: 16292-17-4(Hazardous Substances Data)

Usage

Chemical Properties

Off-white powder

InChI:InChI=1/C12H9Br2N/c13-9-1-5-11(6-2-9)15-12-7-3-10(14)4-8-12/h1-8,15H

Upstream product

• 122-39-4 diphenylamine 
• 382165-80-2 N-nitrosodiphenylamine 
• 114687-18-2 N(C₆H₄Br)2 
• 621-23-8 1,2,3-trimethoxybenzene 
• 5467-74-3 4-Bromophenylboronic acid 
• 106-40-1 4-bromo-aniline 
• 589-87-7 1,4-bromoiodobenzene 
• 106-95-6 allyl bromide 
• 65178-51-0 N-allyldiphenylamine 
• 589-21-9 (4-bromophenyl)hydrazine 
• 583-55-1 1-Bromo-2-iodobenzene 
• 615-36-1 2-bromoaniline 
• 673-40-5 4-bromobenzenediazonium tetrafluoroborate 
• 5149-08-6 1,1-bis(4-bromophenyl)hydrazine 

Downstream Products

• 99234-92-1 N,N-bis-(4-bromophenyl)benzamide 
• 1211-37-6 2,7-dibromoacridine 
• 197144-27-7 4,4’-dibromo-N-(tert-butoxycarbonyl)phenylaniline 
• 81090-53-1 N,N-bis(4-bromophenyl)aniline 
• 116767-41-0 N-butylbis(4-bromophenyl)amine 
• 1039140-39-0 N-heptylbis(4-bromophenyl)amine 
• 1039140-44-7 N-nonylbis(4-bromophenyl)amine 
• 1039140-47-0 N-dodecylbis(4-bromophenyl)amine 
• 1357009-91-6 4-bromo-N-(4-bromophenyl)-N-octylphenylamine 
• 1357009-88-1 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-N-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-N-octylphenylamine 
• 102113-98-4 bis(biphenyl-4-yl)amine 
• 499128-71-1 N-([1′,1′-biphenyl]-4-yl)-N-(4-bromophenyl)-[1,1′-biphenyl]-4-amine 
• 1427738-35-9 C₅₄H₃₆N₂S 
• 1351866-85-7 C₆₀H₄₀N₂ 

Relevant articles and documents

Perovskite Solar Cells Based on Oligotriarylamine Hexaarylbenzene as Hole-Transporting Materials

A cobalt-catalyzed cyclotrimerization of bis(aryl)alkyne is used as an innovative tool to obtain hole-transport materials (HTMs). The novel HTM containing six units of oligotriarylamine (HAB1), characterized by UV-vis, cyclic voltammetry, DFT, and thermogravimetric analysis, confirms its suitability as an efficient HTM in PSCs. A PCE of 17.5% was obtained in HAB1-containing PSCs, a performance comparable to that obtained with spiro-OMeTAD and with slightly better thermal stability.

DMSO-allyl bromide: A mild and efficient reagent for atom economic one-pot: N -allylation and bromination of 2°-aryl amines, 2-aryl aminoamides, indoles and 7-aza indoles

A mixture DMSO-allyl bromide has been developed as a reagent for an atom economic one-pot N-allylation and aryl bromination under basic conditions. Utilizing this reagent, N-allylation-bromination of a number of 2°-aryl amines, aryl aminoamides, indoles, and 7-aza indoles has been achieved. The scope of the substrates and limitations, the synthetic utility of the products, and a plausible reaction mechanism have been proposed.

PYRENE DERIVATIVES AND ORGANIC ELECTRO LUMINESCENT DEVICE COMPRISING SAME

The present invention relates to a pyrene based derivative compound of an asymmetric structure and an organic electroluminescent device comprising the same. The pyrene derivative according to the present invention is characterized by being represented by chemical formula A through chemical formula B. The pyrene derivative compound according to the present invention exhibits remarkably improved blue color purity as compared to an organic electroluminescent device using an existing pyrene based aryl amine derivative compound while being able to realize full color since life characteristic and luminance characteristic are excellent, thereby being able to be used in various display devices.