TOTAL SYNTHESIS OF STEROIDS. PART XV. A NOVEL METHOD OF SYNTHESIS OF β-AMINO KETONES AND VINYL KETONES AND ITS APPLICATION IN TOTAL SYNTHESIS OF ESTROGENS
A new method of synthesizing β-bromo ketones, vinyl ketones and β-N,N-dimethylamino ketones, starting from terminal olefines, diborane and 1-diazo-4-bromo-2-butanone has been described.The above method was utilized in total synthesis of estrogens.
Daniewski, Andrzej R.,Jinaraj, V. K.,Kocor, Marian
p. 2243 - 2246
(2007/10/02)
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