- Synthesis method of hydroxypropyl tetrahydropyrantriol
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The invention provides a synthetic method of hydroxypropyl tetrahydropyrantriol. According to the synthetic method, a product is obtained through a coupling reaction. Compared with other routes, the synthetic method disclosed by the invention has the advantages of higher product yield, better quality, simpler reaction process, easiness in post-treatment and the like, and is suitable for industrial production of hydroxypropyl tetrahydropyrantriol. In addition, the invention also provides a novel raw material for synthesizing the hydroxypropyl tetrahydropyrantriol.
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Paragraph 0049-0053
(2022/03/16)
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- Method for synthesizing glassine by one-pot method
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The invention discloses a method for synthesizing a bose by a one-pot method, which comprises the following step of: synthesizing the bose by the one-pot method under the action of a catalyst and a reducing agent by taking xylose and acetoacetate substances as raw materials in the presence of an organic solvent. The method has the advantages of easily available catalyst and reducing agent, low cost and high yield, and is suitable for industrial production.
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Paragraph 0020-0026
(2021/07/21)
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- Method for synthesizing glassine
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The invention relates to a method for synthesizing a glassine. The method comprises the following steps: reacting (2R, 3S, 4S)-2, 3, 4-tribenzyloxy glutaraldehyde with acetone to synthesize a key intermediate (E)-(2R, 3S, 4S)-2, 3, 4-tribenzyloxy pentyl-6-acetyl hexane-5-olefine aldehyde, then catalyzing (E)-(2R, 3S, 4S)-2, 3, 4-tribenzyloxy pentyl-6-acetyl hexane-5-olefine aldehyde with Lewis acid to sequentially carry out a nucleophilic addition and a 1, 4-Michael addition reactions, obtaining benzyl-protected Pro-Xylane 1-((2S, 3S, 4S, 5R)-3, 4, 5-tri(benzyloxy) tetrahydro-2H-pyran-2-yl)propan-2-ol, and finally, carrying out catalytic hydrogenation by using palladium carbon to remove benzyl, so as to obtain Pro-XylaneTM (2S, 3R, 4S, 5R)-2-(2-hydroxypropyl) tetrahydro-2H-pyran-3, 4, 5-triol. The method is high in reaction yield, the obtained product is high in purity, and the method has huge application value.
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Paragraph 0033; 0038-0049
(2021/05/19)
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- Method for synthesizing cosmetic active material hydroxypropyl tetrahydropyrantriol through one-pot method under promoting of rare earth metal coordination compound
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The invention belongs to the fields of organic synthesis, fine chemicals and daily chemicals, and particularly relates to a method for synthesizing hydroxypropyl tetrahydropyrantriol from xylose and ethyl acetoacetate through a one-pot method under the promoting of a rare earth metal coordination compound. According to the present invention, the method has characteristics of easy operation, inexpensive and easily available reagents and good industrial application prospects.
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Paragraph 0013-0018
(2019/11/29)
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- Synthesis of Pro-XylaneTM: A new biologically active C-glycoside in aqueous media
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The scope and limitation of Lubineau's reaction were evaluated for the synthesis of C-glycosides (compounds 1-13). Further transformation of side chain carbonyl was also achieved (compounds 16-23). Optimization of these two steps was investigated in xylos
- Cavezza, Alexandre,Boulle, Christophe,Gueguiniat, Amelie,Pichaud, Patrick,Trouille, Simon,Ricard, Louis,Dalko-Csiba, Maria
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experimental part
p. 845 - 849
(2009/10/02)
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- Novel C-glycosides, uses thereof
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The present invention relates to novel C-glycoside compounds of given absolute configuration, to a process for synthesising them and to compositions containing them. The invention also relates to the cosmetic use of these C-glycoside compounds as agents t
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Page/Page column 6, 7
(2008/06/13)
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