cas 374-41-4, 3,3,4,4,4-PENTAFLUOROBUTAN-2-ONE | Articles data ｜lookchem

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374-41-4

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(Z) -Trifluoromethyl-Trisubstituted Alkenes or Isoxazolines: Divergent Pathways from the Same Allene
Because of a charge-dipole interaction involving nonbonding electron pairs on fluorine, protonation of trifluoromethyl allenes leads to tri- or tetrasubstituted alkenes with high (Z)-selectivity. Treatment of the same allenes with catalytic Au(I) initiates a reaction cascade that produces isoxazolines in high yield.
Liu, Chaolun,Rowland, Casey A.,Tius, Marcus A.,Yap, Glenn P. A.
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p. 7208 - 7212
(2020/10/02)

2,2-Dihydroperfluoropentane (HFC 4310 mf) synthesis from HFP dimer
The thermodynamic dimer of hexafluoropropene (HFP) may be used for the one pot synthesis of 2H-perfluoro-2-pentene, which is the starting compound for preparation of 2,2-dihydroperfluoropentane (HFC 4310 mf).
Cheburkov, Yuri,Moore, George G.I.
p. 227 - 231
(2007/10/03)

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Chemical Properties

Boiling Point: 33.6 °C at 760 mmHg
Density: 1.361 g/cm³
Vapor Pressure: 549mmHg at 25°C
Refractive Index: 1.286
PSA: 17.07000
LogP: 1.77300

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