A NOVEL REARRANGEMENT OF THE ADDUCT FROM CS-EPOXIDE AND DIOXAN-2-HYDROPEROXIDE
Under mild conditions, nucleophiles add across the cyanide moiety of CS epoxide rather than opening the ring.With hydroxide ion in peroxide-free aqueous dioxan isomeric amides are obtained.Hydrolysis in peroxide containing dioxan affords a novel rearrangement involving carbon-carbon bond fission of the dioxan.
Harrison, John M.,Inch, Thomas D.
p. 679 - 682
(2007/10/02)
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