Silver-catalyzed formal inverse electron-demand diels-alder reaction of 1,2-diazines and siloxy alkynes
A highly effective silver-catalyzed formal inverse electron-demand Diels-Alder reaction of 1,2-diazines and siloxy alkynes has been developed. The reactions provide ready access to a wide range of siloxy naphthalenes and anthracenes, which are formed in good to high yields, under mild reaction conditions, using low catalyst loadings.
Tuerkmen, Yunus E.,Montavon, Timothy J.,Kozmin, Sergey A.,Rawal, Viresh H.