2-Hydroxy-N,N,N-tributylethanaminium thiocyanate as solvent and reagent for the preparation of alkyl thiocyanates
2-Hydroxy-N,N,N-tributylethanaminium thiocyanate was utilized as both solvent and reagent for the conversion of alkyl halides to the corresponding alkyl thiocyanates in good yields under mild conditions.
Mohanazadeh, Farajollah,Aghvami, Magid
p. 7240 - 7242
(2008/03/11)
Optimized access to alkyl thiocyanates
Functionalized alkyl thiocyanates are synthesized in high yields from corresponding halides via in situ formation of tetra n-butylammonium thiocyanate. Use of this mild but efficient thiocyanation reagent limits the amounts of by-products.
Renard, Pierre-Yves,Schwebel, Hervé,Vayron, Philippe,Leclerc, Eric,Dias, Sonia,Mioskowski, Charles
p. 8479 - 8481
(2007/10/03)
Substitution Reaction of Organic Halide by Trimethylsilyl Isothiocyanate: Formation of Thiocyanate and Its Rearrangement to Isothiocyanate
The reaction of organic halide with trimethylsilyl isothiocyanate (TMSTC) gave thiocyanate 1 and its isomerized isothiocyanate 2.Details of the substitution and the isomerization reactions were examined.
Nishiyama, Kozaburo,Oba, Makoto
p. 2692 - 2694
(2007/10/02)
More Articles about upstream products of 1936-96-5